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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Weir, Ron / Stohner, Jürgen


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Guidelines for terms related to chemical speciation and fractionation of elements. Definitions, structural aspects, and methodological approaches (IUPAC Recommendations 2000)

Douglas M. Templeton1 / Freek Ariese2 / Rita Cornelis3 / Lars-Göran Danielsson4 / Herbert Muntau5 / Herman P. van Leeuwen6 / Ryszard Lobinski7

1Department of Laboratory Medicine and Pathobiology, University of Toronto, Canada

2Department of Analytical Chemistry and Applied Spectroscopy, Vrije Universiteit Amsterdam, the Netherlands

3Laboratory for Analytical Chemistry, Faculty of Sciences, University of Gent, Belgium

4Department of Analytical Chemistry, Royal Institute of Technology, Stockholm, Sweden

5Environmental Institute, Joint Research Centre Ispra, (VA) Italy

6Department of Physical Chemistry and Colloid Science, Wageningen Agricultural University, the Netherlands

7CNRS UMR 5034, Hélioparc, Pau, France, and Department of Chemistry, Warsaw University of Technology,Warszawa, Poland

Project Year: 1998, Project Code: 720/13/98

Citation Information: Pure and Applied Chemistry. Volume 72, Issue 8, Pages 1453–1470, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/pac200072081453, January 2009

Publication History

Published Online:
2009-01-01

This paper presents definitions of concepts related to speciation of elements, more particularly speciation analysis and chemical species. Fractionation is distinguished from speciation analysis, and a general outline of fractionation procedures is given. We propose a categorization of species according to isotopic composition of the element, its oxidation and electronic states, and its complex and molecular structure. Examples are given of methodological approaches used for speciation analysis. A synopsis of the methodology of dynamic speciation analysis is also presented.

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