Novel polymerization and copolymerization of ethylene, styrene, and/or butadiene by new organolanthanide-based catalysts

Zhaomin Hou; Shojiro Kaita; Yasuo Wakatsuki

doi:10.1351/pac200173020291

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Novel polymerization and copolymerization of ethylene, styrene, and/or butadiene by new organolanthanide-based catalysts

Zhaomin Hou

Corresponding author
Organometallic Chemistry Laboratory, RIKEN (The Institute of Physical and Chemical Research) , Hirosawa 2-1, Wako, Saitama 351-0198, Japan
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/ Shojiro Kaita

Corresponding author
Organometallic Chemistry Laboratory, RIKEN (The Institute of Physical and Chemical Research) , Hirosawa 2-1, Wako, Saitama 351-0198, Japan
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/ Yasuo Wakatsuki

Corresponding author
Organometallic Chemistry Laboratory, RIKEN (The Institute of Physical and Chemical Research) , Hirosawa 2-1, Wako, Saitama 351-0198, Japan
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Published Online: 2009-01-01 | DOI: https://doi.org/10.1351/pac200173020291

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Replacement of one of the two C₅Me₅ ligands in the samarocene (II) complex (C₅Me₅) ₂Sm (THF) ₂ with a monodentate anionic ligand (e. g. , OAr, SAr, or NR¹R²) gives a unique catalytic system, which can not only polymerize styrene and ethylene, but also copolymerize them into block styrene-ethylene copolymers under the presence of both monomers. On the other hand, addition of an appropriate cocatalyst such as MMAO or AlR₃/[Ph₃C][B (C₆F₅) ₄] to the samarocene complex (C₅Me₅) ₂Sm (THF) ₂ or (C₅Me₅) ₂Sm (m-Me) ₂AlMe₂ affords a novel catalytic system for stereospecific 1,4-cis living polymerization of butadiene and copolymerization of butadiene with styrene.

Conference

International Conference on Organometallic Chemistry (XIX ICOMC), International Conference on Organometallic Chemistry, ICOMC, Organometallic Chemistry, XIXth, Shanghai, China, 2000-07-23–2000-07-28

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Published Online: 2009-01-01

Published in Print: 2001-01-01

Citation Information: Pure and Applied Chemistry, Volume 73, Issue 2, Pages 291–294, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/pac200173020291.

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