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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen


IMPACT FACTOR 2018: 2.350
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CiteScore 2018: 4.66

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1365-3075
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Volume 73, Issue 4

Issues

Organic photochromism (IUPAC Technical Report)

Henri Bouas-Laurent
  • Corresponding author
  • Laboratoire de Chimie Organique et Organométallique, Groupe de Photochimie Organique, CNRS, UMR 5802, Université Bordeaux 1, F-33405 Talence Cedex, France
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Heinz Dürr
  • Corresponding author
  • FR 11.2 Organische Chemie, Universität des Saarlandes, Postfach 151150, D-66041 Saarbrücken, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2009-01-01 | DOI: https://doi.org/10.1351/pac200173040639

This technical report is a general introduction to organic photochromism. The definition of photochromism (PC) is given together with that of words with the ending "chromism", such as thermo-, electro-, piezo-, and tribochromism. Important concepts such as two-photon, gated, dual-mode PC and chirochromism are illustrated. The concept of fatigue (chemical degradation) and the determination of the main photochromic parameters (number of cycles, cyclability, half-life), and the spectrokinetic and mechanistic aspects are discussed. The main families of PC (organic compounds and biological receptors) are illustrated with chemical formulae, and the different types of reactions involved in the photochromic processes (pericyclic reactions, E/Z isomerization, group transfer, etc.) are listed. Some examples of applications to "optical power limiting" substances, photoresponsive materials, and photoswitchable biomaterials are considered.

Project Year: 1998, Project Code: 330/20/98

About the article

Published Online: 2009-01-01

Published in Print: 2001-01-01


Citation Information: Pure and Applied Chemistry, Volume 73, Issue 4, Pages 639–665, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/pac200173040639.

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