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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Weir, Ron / Stohner, Jürgen

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Functionalized main-group organometallics for organic synthesis

Paul Knochel1 / Eike Hupe1 / Wolfgang Dohle1 / David M. Lindsay1 / Véronique Bonnet1 / Guy Quéguiner1 / Andreas Boudier1 / Felix Kopp1 / Stéphane Demay1 / Naka Seidel1 / M. Isabel Calaza1 / Viet Anh Vu1 / Ioannis Sapountzis1 / Tanasri Bunlaksananusorn1

1Ludwig-Maximilians-Universität München, Department Chemie, Butenandtstrasse 5-13, Haus F, 81377 München, Germany


IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS-11), International Symposium on Organometallic Chemistry Directed Toward Organic Synthesis, OMCOS, Organometallic Chemistry Directed Toward Organic Synthesis, 11th, Taipei, Taiwan, 2001-07-22–2001-07-26

Citation Information: Pure and Applied Chemistry. Volume 74, Issue 1, Pages 11–17, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/pac200274010011, January 2009

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Highly functionalized Grignard-reagents can be easily obtained by an iodine­magnesim exchange reaction and further reacted with various electrophiles. Via a B­Zn exchange reaction, a formal Michael addition with umpolung of the reactivity can be achieved. Chiral phosphine ligands can be easily synthesized by a 2.3 sigmatropic rearrangement and used successfully in asymmetric synthesis.

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