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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen


IMPACT FACTOR 2017: 5.294

CiteScore 2017: 3.42

SCImago Journal Rank (SJR) 2017: 1.212
Source Normalized Impact per Paper (SNIP) 2017: 1.546

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ISSN
1365-3075
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Volume 74, Issue 10

Issues

Cation order/disorder in lithium transition-metal oxides as insertion electrodes for lithium-ion batteries

E. Zhecheva
  • Corresponding author
  • Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, 1113 Sofia, Bulgaria
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/ R. Stoyanova
  • Corresponding author
  • Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, 1113 Sofia, Bulgaria
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/ R. Alcántara
  • Corresponding author
  • Laboratorio de Química Inorgánica, Edificio C3, Primera Planta, Campus de Rabanales, Facultad de Ciencias, Universidad de Córdoba, 14071 Córdoba, Spain
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/ P. Lavela
  • Corresponding author
  • Laboratorio de Química Inorgánica, Edificio C3, Primera Planta, Campus de Rabanales, Facultad de Ciencias, Universidad de Córdoba, 14071 Córdoba, Spain
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/ J.-L. Tirado
  • Corresponding author
  • Laboratorio de Química Inorgánica, Edificio C3, Primera Planta, Campus de Rabanales, Facultad de Ciencias, Universidad de Córdoba, 14071 Córdoba, Spain
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Published Online: 2009-01-01 | DOI: https://doi.org/10.1351/pac200274101885

Results on the local cation ordering in layered lithium-nickel/cobalt oxides and metal-substituted lithium-manganese spinels are presented. It is shown that electron spin resonance of Ni3+ and Mn4+ and magnetic susceptibility measurements are powerful tools to monitor the short-range cation ordering in these compounds, which is not accessible by diffraction techniques. Thus, owing to the different strength of the 90° and 180° Ni3+–O–Ni3+/2+ exchange interactions, the distribution of Ni3+/Ni2+ between the lithium and nickel layers in Li1–xNi1+xO2 with 0 < x < 0.4 can be determined. For layered LiNi1–yCoyO2 and spinel LiMn2–xCoxO4 solid solutions, analysis of the temperature-independent EPR line width in terms of dipole–dipole and exchange interactions has been used to examine the local Ni3+/Co3+ and Mn4+/Co3+ ordering. The results obtained are correlated with the electrochemical intercalation of lithium in these compounds.

Conference

International Symposium on Solubility Phenomena, International Symposium on Solubility Phenomena, ISSP, Solubility Phenomena, 10th, Varna, Bulgaria, 2002-07-22–2002-07-26

About the article

Published Online: 2009-01-01

Published in Print: 2002-01-01


Citation Information: Pure and Applied Chemistry, Volume 74, Issue 10, Pages 1885–1894, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/pac200274101885.

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