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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Weir, Ron / Stohner, Jürgen

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Volume 75, Issue 1 (Jan 2003)


Critical evaluation of the chemical properties of the transactinide elements (IUPAC Technical Report)

J. V. Kratz
Published Online: 2009-01-01 | DOI: https://doi.org/10.1351/pac200375010103

In this paper, the chemical properties of the transactinide elements rutherfordium, Rf (element 104); dubnium, Db (element 105); and seaborgium, Sg (element 106) are critically reviewed. The experimental methods for performing rapid chemical separations on a time scale of seconds are reviewed, and comments are given on the special situation with the transactinides for which the chemistry has to be studied with single atoms. There follows a systematic description of theoretical predictions and experimental results on the chemistry of Rf, Db, and Sg - their mutual comparison and evaluation. The literature cited has the cutoff date of March 1999. The more recent chemical identification of bohrium, Bh (element 107), and of hassium, Hs (element 108), should be evaluated in a future Part II of this report.

Project Year: 2001, Project Code: 2001-071-1-500

About the article

Published Online: 2009-01-01

Published in Print: 2003-01-01

Citation Information: Pure and Applied Chemistry, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/pac200375010103. Export Citation

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