Jump to ContentJump to Main Navigation
Show Summary Details
More options …

Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Weir, Ron / Stohner, Jürgen

12 Issues per year


IMPACT FACTOR 2016: 2.626
5-year IMPACT FACTOR: 3.210

CiteScore 2016: 2.45

SCImago Journal Rank (SJR) 2016: 0.972
Source Normalized Impact per Paper (SNIP) 2016: 1.049

Online
ISSN
1365-3075
See all formats and pricing
More options …
Volume 76, Issue 3

Issues

Stereochemistry of epoxide carbonylation using bimetallic Lewis acid/metal carbonyl complexes

Y. D. Y. L. Getzler
  • Corresponding author
  • Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Viswanath Mahadevan
  • Corresponding author
  • Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ E. B. Lobkovsky
  • Corresponding author
  • Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ G. W. Coates
  • Corresponding author
  • Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2009-01-01 | DOI: https://doi.org/10.1351/pac200476030557

The stereochemistry of epoxide carbonylation using bimetallic [Lewis acid]+[Co(CO)4]- complexes is reported. The achiral complex [(salph)Al(THF)2][Co(CO)4] stereospecifically carbonylates cis- and trans-2-butene oxide to the trans- and cis-β-lactones, respectively. Preliminary experiments regarding the carbonylative kinetic resolution of racemic trans-2-butene oxide using the enantiomerically pure complex [(R,R-salcy)Al(THF)2][Co(CO)4] are also reported.

Conference

International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS-12), International Symposium on Organometallic Chemistry Directed Toward Organic Synthesis, OMCOS, Organometallic Chemistry Directed Toward Organic Synthesis, 12th, Toronto, Ontario, Canada, 2003-07-06–2003-07-10

About the article

Published Online: 2009-01-01

Published in Print: 2004-01-01


Citation Information: Pure and Applied Chemistry, Volume 76, Issue 3, Pages 557–564, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/pac200476030557.

Export Citation

© 2013 Walter de Gruyter GmbH, Berlin/Boston. Copyright Clearance Center

Citing Articles

Here you can find all Crossref-listed publications in which this article is cited. If you would like to receive automatic email messages as soon as this article is cited in other publications, simply activate the “Citation Alert” on the top of this page.

[1]
Jessica R. Lamb, Michael Mulzer, Anne M. LaPointe, and Geoffrey W. Coates
Journal of the American Chemical Society, 2015, Volume 137, Number 47, Page 15049
[2]
J. P. MacDonald, M. P. Parker, B. W. Greenland, D. Hermida-Merino, I. W. Hamley, and M. P. Shaver
Polym. Chem., 2015, Volume 6, Number 9, Page 1445
[3]
Michael Mulzer, Jessica R. Lamb, Zachary Nelson, and Geoffrey W. Coates
Chemical Communications, 2014, Volume 50, Number 69, Page 9842
[4]
Michael Mulzer, W. Chadwick Ellis, Emil B. Lobkovsky, and Geoffrey W. Coates
Chemical Science, 2014, Volume 5, Number 5, Page 1928
[5]
Maria O. Miranda, Yvonne DePorre, Hugo Vazquez-Lima, Michelle A. Johnson, Daniel J. Marell, Christopher J. Cramer, and William B. Tolman
Inorganic Chemistry, 2013, Volume 52, Number 23, Page 13692
[6]
Qijia FAN, Jianhua LIU, Jing CHEN, and Chungu XIA
CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), 2013, Volume 33, Number 9, Page 1435
[7]
Prasad Ganji and Hasim Ibrahim
Chemical Communications, 2012, Volume 48, Number 81, Page 10138
[8]
John W. Kramer, Emil B. Lobkovsky, and Geoffrey W. Coates
Organic Letters, 2006, Volume 8, Number 17, Page 3709
[9]
Hongyu Xu, Jeffery A. Gladding, and Li Jia
Inorganica Chimica Acta, 2004, Volume 357, Number 13, Page 4024
[10]
Heimo Wölfle, Holger Kopacka, Klaus Wurst, Peter Preishuber-Pflügl, and Benno Bildstein
Journal of Organometallic Chemistry, 2009, Volume 694, Number 16, Page 2493
[11]
Jianhua Liu, Jing Chen, and Chungu Xia
Journal of Molecular Catalysis A: Chemical, 2006, Volume 250, Number 1-2, Page 232
[12]
Jianhua Liu, Hugjiltu Wu, Liwen Xu, Jing Chen, and Chungu Xia
Journal of Molecular Catalysis A: Chemical, 2007, Volume 269, Number 1-2, Page 97
[13]
Yessi Permana, Koji Nakano, Makoto Yamashita, Daisuke Watanabe, and Kyoko Nozaki
Chemistry – An Asian Journal, 2008, Volume 3, Number 4, Page 710
[14]
Tamara L. Church, Yutan D. Y. L. Getzler, Christopher M. Byrne, and Geoffrey W. Coates
Chemical Communications, 2007, Number 7, Page 657

Comments (0)

Please log in or register to comment.
Log in