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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen


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Volume 78, Issue 7

Issues

Boron as a key component for new π-electron materials

Shigehiro Yamaguchi
  • Corresponding author
  • Department of Chemistry, Graduate School of Science, Nagoya University, and SORST, Japan Science and Technology Agency, Chikusa, Nagoya 464-8602, Japan
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Atsushi Wakamiya
  • Corresponding author
  • Department of Chemistry, Graduate School of Science, Nagoya University, and SORST, Japan Science and Technology Agency, Chikusa, Nagoya 464-8602, Japan
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2009-01-01 | DOI: https://doi.org/10.1351/pac200678071413

For the molecular design of new π-electron materials, the incorporation of main group elements into the π-conjugated frameworks is a powerful approach to modifying the nature of the parent π-conjugated systems. In particular, the group 13 boron is of interest, since the boron element has several characteristic features, such as an effective orbital interaction with the π-conjugated frameworks through the vacant p-orbital (i.e., pπ-π* conjugation), high Lewis acidity, and trigonal planar geometry. By exploiting these features of the boron atom, we have designed and synthesized several types of new π-electron materials, including trianthrylborane- or dibenzoborole-based π-conjugated systems as a new fluoride ion sensor, boryl-substituted thienylthiazole as a new building unit for electron-transporting materials, and B,B',B''-trianthrylborazine (B3N3)-based materials as a model of the bundled system of π-conjugated frameworks.

Keywords: borazine; boron; electron-transporting materials; fluoride ion sensors; p-π* conjugation

Conference

International Meeting on Boron Chemistry (IMEBORON-XII), International Symposium on Boron Chemistry, IMEB, Boron Chemistry, 12th, Sendai, Japan, 2005-09-11–2005-09-15

About the article

Published Online: 2009-01-01

Published in Print: 2006-01-01


Citation Information: Pure and Applied Chemistry, Volume 78, Issue 7, Pages 1413–1424, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/pac200678071413.

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