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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen


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Volume 79, Issue 11

Issues

Recent progress on photoreactions in microreactors

Yoshihisa Matsushita
  • Corresponding author
  • Department of Chemistry, Tokyo Institute of Technology, 2-12-1 Ohokayama, Meguro, Tokyo 152-8551, Japan
  • Other articles by this author:
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/ Teijiro Ichimura
  • Corresponding author
  • Department of Chemistry and Materials Science, Tokyo Institute of Technology, 2-12-1 Ohokayama, Meguro, Tokyo 152-8551, Japan
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/ Nobuko Ohba
  • Corresponding author
  • Department of Chemistry and Materials Science, Tokyo Institute of Technology, 2-12-1 Ohokayama, Meguro, Tokyo 152-8551, Japan
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/ Shinji Kumada
  • Corresponding author
  • Department of Chemistry and Materials Science, Tokyo Institute of Technology, 2-12-1 Ohokayama, Meguro, Tokyo 152-8551, Japan
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/ Kosaku Sakeda
  • Corresponding author
  • Department of Chemistry and Materials Science, Tokyo Institute of Technology, 2-12-1 Ohokayama, Meguro, Tokyo 152-8551, Japan
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/ Tadashi Suzuki
  • Corresponding author
  • Department of Chemistry and Materials Science, Tokyo Institute of Technology, 2-12-1 Ohokayama, Meguro, Tokyo 152-8551, Japan
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/ Hideki Tanibata / Toshiaki Murata
Published Online: 2009-01-01 | DOI: https://doi.org/10.1351/pac200779111959

A microreaction system for organic photoreactions was developed, and the processes of diastereo-differentiating photosensitized reaction, photocatalytic oxidation and reduction of organic compounds, and amine N-alkylation were examined in microspace. These model reactions proceeded very rapidly with considerably large photonic efficiencies because of some distinct properties of microreactors for photoreactions, such as higher spatial illumination homogeneity and better light penetration through the entire reactor depth, and large surface-to-volume ratio in comparison with large-scale batch reactors. These results suggest feasibility of microreaction systems on organic photoreactions.

Keywords: asymmetric reaction; endocrine disrupters; photocatalyst; photochemistry; spectroscopy

Conference

International IUPAC Conference on Green-Sustainable Chemistry, IUPAC International Conference on Green Chemistry, ICGC, Green Chemistry , 1st, Dresden, Germany, 2006-09-10–2006-09-15

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About the article

Published Online: 2009-01-01

Published in Print: 2007-01-01


Citation Information: Pure and Applied Chemistry, Volume 79, Issue 11, Pages 1959–1968, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/pac200779111959.

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