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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen


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Volume 79, Issue 2

Issues

Modified mesoporous materials as Pd scavengers and catalyst supports

Cathleen M. Crudden
  • Corresponding author
  • Department of Chemistry, Queen's University, 90 Bader Lane, Kingston, Ontario K7L 3N6, Canada
  • Other articles by this author:
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/ Kevin McEleney
  • Corresponding author
  • Department of Chemistry, Queen's University, 90 Bader Lane, Kingston, Ontario K7L 3N6, Canada
  • Other articles by this author:
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/ Stephanie L. MacQuarrie
  • Corresponding author
  • Department of Chemistry, Queen's University, 90 Bader Lane, Kingston, Ontario K7L 3N6, Canada
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/ Alexandre Blanc
  • Corresponding author
  • Department of Chemistry, Queen's University, 90 Bader Lane, Kingston, Ontario K7L 3N6, Canada
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/ Mutyala Sateesh
  • Corresponding author
  • Department of Chemistry, Queen's University, 90 Bader Lane, Kingston, Ontario K7L 3N6, Canada
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/ Jonathan D. Webb
  • Corresponding author
  • Department of Chemistry, Queen's University, 90 Bader Lane, Kingston, Ontario K7L 3N6, Canada
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  • De Gruyter OnlineGoogle Scholar
Published Online: 2009-01-01 | DOI: https://doi.org/10.1351/pac200779020247

The use of mesoporous molecular sieves (MMSs) modified by mercaptopropyl trimethoxysilane (MPTMS) to scavenge Pd is described. The ordered mesoporous material displays excellent ability to remove Pd from organic and aqueous solutions. After only one treatment, a 500-ppm solution of PdCl2 in water can be reduced to 1 ppb. In addition, the resulting material is an effective, leach-proof catalyst for the Suzuki-Miyaura and Mizoroki-Heck reactions. Thus, the Suzuki-Miyaura reaction can be conducted in water at 80 °C with as little as 3 ppb Pd leaching. Hot filtrations and three-phase tests confirm that the catalyst acts without leaching Pd from the surface.

Keywords: coupling reactions; heterogeneous; micelle-templated materials; ordered materials; palladium; SBA-15

Conference

International Conference on Organic Synthesis (ICOS-16), International Conference on Organic Synthesis, ICOS, Organic Synthesis, 16th, Mérida, Yucatán, México, 2006-06-11–2006-06-15

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About the article

Published Online: 2009-01-01

Published in Print: 2007-01-01


Citation Information: Pure and Applied Chemistry, Volume 79, Issue 2, Pages 247–260, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/pac200779020247.

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