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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen

12 Issues per year


IMPACT FACTOR 2017: 5.294

CiteScore 2017: 3.42

SCImago Journal Rank (SJR) 2017: 1.212
Source Normalized Impact per Paper (SNIP) 2017: 1.546

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1365-3075
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Volume 79, Issue 6

Issues

Addition reactions of E-E and E-H bonds to triple bond of alkynes catalyzed by Pd, Pt, and Ni complexes (E=S, Se)

Irina P. Beletskaya
  • Corresponding author
  • Chemistry Department, Lomonosov Moscow State University, Vorob'evy gory, Moscow, 119899, Russia
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Valentine P. Ananikov
  • Corresponding author
  • Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect 47, Moscow, 119991, Russia
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2009-01-01 | DOI: https://doi.org/10.1351/pac200779061041

The synthetic application and mechanistic aspects of transition-metal (Ni, Pd, Pt) catalyzed addition of E-E and E-H (E=S, Se) bonds to alkynes were investigated in detail. This study revealed major factors controlling the selectivity of such addition reactions. A new Ni-based catalytic system with a self-organized nanostructured catalyst has been designed to perform chemical transformation in high yield, under mild conditions.

Keywords: addition reactions; green chemistry; selenium species; sulfur species; transition-metal catalysis

Conference

IUPAC International Conference on Physical Organic Chemistry (ICPOC-18), International Conference on Physical Organic Chemistry, ICPOC, Physical Organic Chemistry, 18th, Warsaw, Poland, 2006-08-20–2006-08-25

References

About the article

Published Online: 2009-01-01

Published in Print: 2007-01-01


Citation Information: Pure and Applied Chemistry, Volume 79, Issue 6, Pages 1041–1056, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/pac200779061041.

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