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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Weir, Ron / Stohner, Jürgen

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Research on a gel polymer electrolyte for Li-ion batteries

Guangchao Li1 / Zhaohui Li1 / Peng Zhang1 / Hanping Zhang1 / Yuping Wu1

1Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China


International Symposium on Novel Materials and Their Synthesis (NMS-III) and the 17th International Symposium on Fine Chemistry and Functional Polymers (FCFP-XVII), Novel Materials and their Synthesis, NMS, Novel Materials and their Synthesis, 3rd, Shanghai, China, 2007-10-17–2007-10-21

Citation Information: Pure and Applied Chemistry. Volume 80, Issue 11, Pages 2553–2563, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: 10.1351/pac200880112553, January 2009

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Published Online:

The preparation, physical, and electrochemical properties of Li-ion conducting membranes, poly(vinylidene fluoride-co-hexafluoropropylene) [P(VDF-HFP)]-based gel polymer electrolytes, are briefly reviewed in this paper. Phase separation or inversion method is mostly used to prepare microporous membranes because of the flexibility of its operation and controllable pore structure. The crystallinity of the polymer matrix and the pore structure of the membrane are the key issues to prepare P(VDF-HFP)-based gel polymer electrolytes with high Li+ conductivity and good mechanical strength. As to their further directions, they are also discussed.

Keywords: lithium-ion batteries; microporous membranes; polymer electrolytes; P(VDF-HFP); structure control

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