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Pure and Applied Chemistry

The Scientific Journal of IUPAC

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Volume 80, Issue 2


Structure-based nomenclature for cyclic organic macromolecules (IUPAC Recommendations 2008)

W. Mormann
  • Corresponding author
  • Universität Siegen, FB 8, Laboratorium für Makromolekulare Chemie, Adolf-Reichwein-Str. 2, 57076 Siegen, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ K.-H. Hellwich
Published Online: 2009-01-01 | DOI: https://doi.org/10.1351/pac200880020201

A structure-based nomenclature system for monocyclic and polycyclic organic macromolecules is presented. Single-strand mono- and polycyclic macromolecules as well as spiro macrocyclic compounds are covered. However, rotaxanes and catenanes, which contain interlocked rings, and rings or ring systems formed by noncovalent bonds are excluded. Also, polypeptides and carbohydrate polymers are not included. The nomenclature of cyclic macromolecules is based on the existing nomenclature of regular and irregular macromolecules, which in turn is based on the nomenclature of organic chemistry also published by IUPAC. The procedure for naming a cyclic macromolecule consists of transforming it to an open-chain regular or irregular macromolecule in such a way that naming of units proceeds in descending order of seniority but otherwise follows the rules established for these types of macromolecules. For polycyclic macromolecules, the same principles are followed after the main ring, bridges, and branch units are identified and locants for branch units as well as bridges are assigned. The complete names are assembled by citing the component names and locants in the appropriate order according to the rules in this document. Wherever possible, examples for illustration of the naming procedure have been chosen from the literature.

Keywords: examples; IUPAC Chemical Nomenclature and Structure Representation Division; IUPAC Polymer Division; monocyclic macromolecules; nomenclature; polycyclic macromolecules; rules; spiro macromolecules; structure-based nomenclature

Project Year: 2001, Project Code: 2001-082-1-800


  • 1.

    , J. Kahovec. Pure Appl. Chem. 74, 1921 (2002); see also <http://www.chem.qmul.ac.uk/iupac/rssop/>.CrossrefGoogle Scholar

  • 2.

    , R. B. Fox, N. M. Bikales, K. Hatada, J. Kahovec. Pure Appl. Chem. 66, 873 (1994).CrossrefGoogle Scholar

  • 3.

    , R. B. Fox. J. Chem. Inf. Comput. Sci. 24, 266 (1984).CrossrefGoogle Scholar

  • 4.

    IUPAC. Nomenclature of Organic Chemistry, Sections A, B, C, D, E, F and H (the "Blue Book"), prepared for publication by J. Rigaudy and S. P. Klesney, Pergamon Press, Oxford (1979);(a) Spiro hydrocarbons, p. 37; (b) rule B-1.1, p. 53; D-1.61, p. 334; Table I, Appendix, pp. 459-460.Google Scholar

  • 5.

    IUPAC. A Guide to IUPAC Nomenclature of Organic Compounds, prepared for publication by R.Panico, W. H. Powell, and J.-C. Richer, Blackwell Scientific, Oxford (1993); <http://www.acdlabs.com/iupac/nomenclature>; (a) R-, note 29; (b) R-2.4.3; (c) R-; (d) Table 3, rule R-2.3.3, p. 42; rule R-9.3, p. 182.Google Scholar

  • 6.

    H. A. Favre, K.-H. Hellwich, G. P. Moss, W. H. Powell, J. G. Traynham. Pure Appl. Chem. 71, 1327 (1999).Google Scholar

  • 7.

    , Y. Tezuka, H. Oike. J. Am. Chem. Soc. 123, 11570 (2001).CrossrefGoogle Scholar

  • 8.

    , Y. Tezuka. Chem. Rec. 5, 17 (2005).CrossrefGoogle Scholar

  • 9.

    IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"), compiled by A. D. McNaught and A. Wilkinson, Blackwell Science, Oxford (1997). XML on-line corrected version: <http://goldbook.iupac.org> (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins.Google Scholar

  • 10.

    , A. D. Jenkins, P. Kratochvil, R. F. T. Stepto, U. W. Suter. Pure Appl. Chem. 68, 2287 (1996).CrossrefGoogle Scholar

  • 11.

    , G. P. Moss. Pure Appl. Chem. 71, 513 (1999); see also <http://www.chem.qmul.ac.uk/iupac/vonBaeyer/>.CrossrefGoogle Scholar

  • 12.

    IUPAC. "Nomenclature of rotaxanes and pseudorotaxanes" (document in preparation).Google Scholar

  • 13.

    , G. P. Moss. Pure Appl. Chem. 71, 531 (1999); see also <http://www.chem.qmul.ac.uk/iupac/spiro/>.CrossrefGoogle Scholar

  • 14. (a)

    IUPAC. Nomenclature of Inorganic Chemistry, IUPAC Recommendations 2005 (the "Red Book"), N. G. Connelly, T. Damhus, R. M. Hartshorn, A. T. Hutton (Eds.), The Royal Society of Chemistry, Cambridge (2005); rule IR-, p. 42; Table VI, appendix, p. 260;Google Scholar

  • 14. (b)

    IUPAC. Nomenclature of Inorganic Chemistry, IUPAC Recommendations 1990, G. J. Leigh (Ed.), Blackwell Scientific, Oxford, UK (1990); rule I-2.15.4, p. 31; Table IV, appendix, p. 244; Table VI, appendix, p. 246.Google Scholar

  • 15.

    G. P. Moss. Pure Appl. Chem. 70, 143 (1998); see also <http://www.chem.qmul.ac.uk/iupac/>.Google Scholar

  • 16. (a)

    , A. Horbach, H. Vernaleken, K. Weirauch. Makromol. Chem. 181, 111 (1980);CrossrefGoogle Scholar

  • 16. (b)

    , H. R. Kricheldorf, S. Bohme, G. Schwarz, C.-L. Schultz. Macromol. Rapid Commun. 23, 803 (2002).CrossrefGoogle Scholar

  • 17.

    , C. W. Bielawski, D. Benitez, R. H. Grubbs. Science 297, 2041 (2002).CrossrefGoogle Scholar

  • 18.

    , K. Ishizu, Y. Akiyama. Polymer 38, 491 (1997).CrossrefGoogle Scholar

  • 19.

    , H. R. Kricheldorf, L. Vakhtangishvili, G. Schwarz, G. Schulz, R.-P. Kruger. Polymer 44, 4471 (2003).CrossrefGoogle Scholar

  • 20.

    , Y. Tezuka, A. Tsuchitani, Y. Yoshioka, H. Oike. Macromolecules 36, 65 (2003).CrossrefGoogle Scholar

  • 21.

    , H. R. Kricheldorf, S. Rost. Macromol. Chem. Phys. 205, 1031 (2004).CrossrefGoogle Scholar

  • 22.

    , H. Oike, M. Hamada, S. Eguchi, Y. Danda, Y. Tezuka. Macromolecules 34, 2776 (2001).CrossrefGoogle Scholar

  • 23.

    , H. R. Kricheldorf, S. Rost. Macromolecules 37, 7955 (2004).CrossrefGoogle Scholar

About the article

Published Online: 2009-01-01

Published in Print: 2008-01-01

Citation Information: Pure and Applied Chemistry, Volume 80, Issue 2, Pages 201–232, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/pac200880020201.

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