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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen

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Volume 80, Issue 7

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Synthesis and applications of functionalized silsesquioxane polymers attached to organic and inorganic matrices

Yoshitaka Gushikem
  • Corresponding author
  • Institute of Chemistry, Campinas State University, CP 6154, 13084-971, Campinas, SP, Brazil; Institute of Chemistry, Rio Grande do Sul National University, 91501-970, Porto Alegre, RS, Brazil; V. N. Karazin Kharkiv National University, 4 Svoboda Square, Kharkiv, 61077, Ukraine
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Edilson V. Benvenutti
  • Corresponding author
  • Institute of Chemistry, Campinas State University, CP 6154, 13084-971, Campinas, SP, Brazil; Institute of Chemistry, Rio Grande do Sul National University, 91501-970, Porto Alegre, RS, Brazil; V. N. Karazin Kharkiv National University, 4 Svoboda Square, Kharkiv, 61077, Ukraine
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Yuriy V. Kholin
  • Corresponding author
  • Institute of Chemistry, Campinas State University, CP 6154, 13084-971, Campinas, SP, Brazil; Institute of Chemistry, Rio Grande do Sul National University, 91501-970, Porto Alegre, RS, Brazil; V. N. Karazin Kharkiv National University, 4 Svoboda Square, Kharkiv, 61077, Ukraine
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2009-01-01 | DOI: https://doi.org/10.1351/pac200880071593

Organofunctionalized silsesquioxane polymers obtained in a water-soluble form can be used to coat various substrates such as SiO2, SiO2/Al2O3, Al2O3, cellulose/Al2O3, and graphite or, when obtained in a water-insoluble form, can be used directly. These organofunctionalized silsesquioxanes can also be attached to poly(dimethylsiloxane) (PDMS) polymers. The functional groups constituted by neutral amine groups or cationic groups (pyridinium, 3- and 4-picolinium, or 1,4-diazabicyclo[2.2.2]octane (DABCO), mono- or -dicationic) have relatively high affinity for metal ion in ethanol solutions, as shown by their stability constants. Materials containing attached cationic functional groups have also been efficiently used to immobilize various electroactive species and to construct electrochemical sensors for analytical applications. This work discusses the preparation of silsesquioxane derivatives, their characterization as prepared and when dispersed on several substrates, and comments on some applications of these materials, with an emphasis on the metal adsorption process and manufacture of electrochemical sensors.

Keywords: adsorption; chemically modified surfaces; electrochemical sensors; organofunctionalized silsesquioxane polymers; silsesquioxane polymers; sol-gel

Conference

International Conference on Modern Physical Chemistry for Advanced Materials (MPC '07), Kharkiv, Ukraine, 2007-06-26–2007-06-30

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About the article

Published Online: 2009-01-01

Published in Print: 2008-01-01


Citation Information: Pure and Applied Chemistry, Volume 80, Issue 7, Pages 1593–1611, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/pac200880071593.

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