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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen


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1365-3075
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Volume 80, Issue 8

Issues

Chemoselective reactions: Toward the synthesis of biologically active natural products with anticancer activities

Sébastien Reymond
  • Corresponding author
  • Laboratoire de Chimie Organique ESPCI-Paris Tech, CNRS, 10 Rue Vauquelin, 75231 Paris Cedex 05, France
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Laurent Ferrié
  • Corresponding author
  • Laboratoire de Chimie Organique ESPCI-Paris Tech, CNRS, 10 Rue Vauquelin, 75231 Paris Cedex 05, France
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/ Amandine Guérinot
  • Corresponding author
  • Laboratoire de Chimie Organique ESPCI-Paris Tech, CNRS, 10 Rue Vauquelin, 75231 Paris Cedex 05, France
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/ Patrice Capdevielle
  • Corresponding author
  • Laboratoire de Chimie Organique ESPCI-Paris Tech, CNRS, 10 Rue Vauquelin, 75231 Paris Cedex 05, France
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/ Janine Cossy
  • Corresponding author
  • Laboratoire de Chimie Organique ESPCI-Paris Tech, CNRS, 10 Rue Vauquelin, 75231 Paris Cedex 05, France
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Published Online: 2009-01-01 | DOI: https://doi.org/10.1351/pac200880081683

Leucascandrolide A and migrastatin were synthesized efficiently by using chemoselective reactions such as olefin metatheses. The use of an iron-catalyzed cross-coupling reaction overcame difficulties encountered with palladium-catalyzed processes in our synthetic approach toward spirangien A.

Keywords: allyltitanation; chemoselective reactions; cross-coupling; cross-metathesis; crotyltitanation; iron; natural products; ring-closing metathesis; total synthesis

Conference

IUPAC World Chemistry Congress, IUPAC Congress, CONGRESS, IUPAC Congress, 41st, Turin, Italy, 2007-08-05–2007-08-11

References

About the article

Published Online: 2009-01-01

Published in Print: 2008-01-01


Citation Information: Pure and Applied Chemistry, Volume 80, Issue 8, Pages 1683–1691, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/pac200880081683.

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