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Pure and Applied Chemistry

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Volume 81, Issue 11 (Oct 2009)

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Development of efficient processes under flow conditions based on catalysts immobilized onto monolithic supported ionic liquid-like phases

M. Isabel Burguete
  • Corresponding author
  • Department of Inorganic and Organic Chemistry, A.U. for Advanced Organic Materials, University Jaume I/CSIC, Avda. Sos Baynat s/n. E-12071 Castellón, Spain
/ Eduardo García-Verdugo
  • Corresponding author
  • Department of Inorganic and Organic Chemistry, A.U. for Advanced Organic Materials, University Jaume I/CSIC, Avda. Sos Baynat s/n. E-12071 Castellón, Spain
/ Naima Karbass
  • Corresponding author
  • Department of Inorganic and Organic Chemistry, A.U. for Advanced Organic Materials, University Jaume I/CSIC, Avda. Sos Baynat s/n. E-12071 Castellón, Spain
/ Santiago V. Luis
  • Corresponding author
  • Department of Inorganic and Organic Chemistry, A.U. for Advanced Organic Materials, University Jaume I/CSIC, Avda. Sos Baynat s/n. E-12071 Castellón, Spain
/ Victor Sans
  • Corresponding author
  • Department of Inorganic and Organic Chemistry, A.U. for Advanced Organic Materials, University Jaume I/CSIC, Avda. Sos Baynat s/n. E-12071 Castellón, Spain
/ Maia Sokolova
  • Corresponding author
  • Department of Inorganic and Organic Chemistry, A.U. for Advanced Organic Materials, University Jaume I/CSIC, Avda. Sos Baynat s/n. E-12071 Castellón, Spain
Published Online: 2009-10-15 | DOI: https://doi.org/10.1351/PAC-CON-08-11-02

The introduction of imidazolium subunits into polystyrene-divinylbenzene (PS-DVB) polymers enables the preparation of a variety of catalytic systems. Those include the stabilization of catalytically active Pd nanoparticles (PdNPs), immobilized enzymes, and basic catalysts. The use of monolithic supports having the appropriate morphological properties is greatly advantageous for the development of efficient catalytic processes under flow conditions based on those systems. On the other hand, the combination of those supported catalytic systems and flow conditions can be further implemented, in terms of green chemistry, by the substitution of the use of traditional solvents by environmentally friendly conditions such as the use of supercritical fluids (SCFs).

Keywords: flow chemistry; functional polymers; green chemistry; Heck reaction; ionic liquids; supercritical liquids; supported biocatalysts; supported catalysts

Conference

International Conference on Green Chemistry (ICGC-2), IUPAC International Conference on Green Chemistry, ICGC, Green Chemistry , 2nd, Moscow, Russia, 2008-09-14–2008-09-20

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About the article

Published Online: 2009-10-15

Published in Print: 2009-10-15


Citation Information: Pure and Applied Chemistry, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/PAC-CON-08-11-02.

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