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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen


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1365-3075
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Volume 81, Issue 4

Issues

Photochemical routes to silver and gold nanoparticles

Juan C. Scaiano
  • Corresponding author
  • Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Ontario K1N 6N5, Canada
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/ Paul Billone
  • Corresponding author
  • Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Ontario K1N 6N5, Canada
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/ Carlos M. Gonzalez
  • Corresponding author
  • Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Ontario K1N 6N5, Canada
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/ Luca Marett
  • Corresponding author
  • Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Ontario K1N 6N5, Canada
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/ M. Luisa Marin
  • Corresponding author
  • Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Ontario K1N 6N5, Canada
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/ Katherine L. McGilvray
  • Corresponding author
  • Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Ontario K1N 6N5, Canada
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/ Nathan Yuan
  • Corresponding author
  • Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Ontario K1N 6N5, Canada
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Published Online: 2009-01-01 | DOI: https://doi.org/10.1351/PAC-CON-08-09-11

The photochemistry of aromatic ketones through the Norrish type I cleavage of benzoins and via photoreduction generates ketyl radicals that readily reduce many metal ions, including silver and gold. Reduction to Au(0) and Ag(0) leads to the spontaneous formation of nanoparticles (NPs) in aqueous or micellar solutions. Careful consideration of kinetic factors to minimize triplet quenching by metal ions can lead to rapid NP generation. These materials are quite stable and have interesting reactivities due to the essentially unprotected characteristics of the surface.

Keywords: benzophenone; nanomaterials; nanoparticles; particle synthesis; photochemistry

Conference

International Conference on Physical Organic Chemistry (ICPOC-19), International Conference on Physical Organic Chemistry, ICPOC, Physical Organic Chemistry, 19th, Santiago de Compostela, Spain, 2008-07-13–2008-07-18

References

About the article

Published Online: 2009-01-01

Published in Print: 2009-01-01


Citation Information: Pure and Applied Chemistry, Volume 81, Issue 4, Pages 635–647, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/PAC-CON-08-09-11.

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