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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen

IMPACT FACTOR 2017: 5.294

CiteScore 2017: 3.42

SCImago Journal Rank (SJR) 2017: 1.212
Source Normalized Impact per Paper (SNIP) 2017: 1.546

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Volume 81, Issue 7


[ONNO]-type amine bis(phenolate)-based vanadium catalysts for ethylene homo- and copolymerization

Christian Lorber
  • Corresponding author
  • a) CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, F-31077 Toulouse; b) Université de Toulouse, UPS, INPT, LCC, F-31077 Toulouse, France
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Published Online: 2009-06-29 | DOI: https://doi.org/10.1351/PAC-CON-08-08-05

The synthesis and solution and solid-state structural characterization of a family of amine bis(phenolate) [ONNO]-vanadium complexes is reviewed. These compounds have oxidation states ranging from vanadium(II) to vanadium(V), and were evaluated as olefin polymerization catalysts. In association with EtAlCl2 cocatalyst, we studied the homopolymerization of ethylene, propene, and 1-hexene, as well as the copolymerization of ethylene with α-olefins (1-hexene, 1-octene) and cycloolefins (norbornene, cyclopentene). Some of these catalysts were shown to produce copolymers with a good activity and comonomer content.

Keywords: amine bis(phenolate); copolymerization; olefins; polymerization; vanadium


International Symposium on Chemistry and Biological Chemistry of Vanadium, International Vanadium Symposium, V, Vanadium , 6th, Lisbon, Portugal, 2008-07-17–2008-07-19


About the article

Published Online: 2009-06-29

Published in Print: 2009-06-30

Citation Information: Pure and Applied Chemistry, Volume 81, Issue 7, Pages 1205–1215, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/PAC-CON-08-08-05.

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