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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen


IMPACT FACTOR 2017: 5.294

CiteScore 2017: 3.42

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1365-3075
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Volume 81, Issue 9

Issues

Dispersion of antimony from oxidizing ore deposits

Glen A. Diemar
  • Corresponding author
  • School of Natural Sciences, University of Western Sydney, Locked Bag 1797, Penrith South DC NSW 1797, Australia
  • Other articles by this author:
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/ Montserrat Filella
  • Corresponding author
  • Département de Chimie Minérale, Analytique et Appliquée, Université de Genève, Quai Ernest-Ansermet 30, CH-1211 Genève 4, Switzerland
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Peter Leverett
  • Corresponding author
  • School of Natural Sciences, University of Western Sydney, Locked Bag 1797, Penrith South DC NSW 1797, Australia
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Peter A. Williams
  • Corresponding author
  • School of Natural Sciences, University of Western Sydney, Locked Bag 1797, Penrith South DC NSW 1797, Australia
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2009-08-04 | DOI: https://doi.org/10.1351/PAC-CON-08-10-21

The solubilities of brandholzite, [Mg(H2O)6][Sb(OH)6]2, and bottinoite, [Ni(H2O)6][Sb(OH)6]2, at 25 °C in water have been measured. Solubilities are 1.95(4) × 10-3 and 3.42(11) × 10-4 mol dm-3, respectively. The incongruent dissolution of romeite, Ca2Sb2O7, and bindheimite, Pb2Sb2O7, at 25 °C in 0.100 mol dm-3 aqueous HNO3 was also investigated. Equilibrium dissolved Sb concentrations were 3.3 ± 1.0 × 10-7 and 7.7 ± 2.1 × 10-8 mol dm-3, respectively. These values have been used to re-evaluate the geochemical mobility of Sb in the supergene environment. It is concluded that the element is geochemically immobile in solution and in soils. This was in part validated by an orientation soil geochemical survey over the Bayley Park prospect near Armidale, New South Wales, Australia. Anomalous soil Sb levels are confined to within 100 m of known stibnite mineralization.

Keywords: antimony; bindheimite; bottinoite; brandholzite; exploration geochemistry; mobility; mopungite; romeite; soils; solubility

Conference

International Symposium on Solubility Phenomena and Related Equilibrium Processes (ISSP-13), International Symposium on Solubility Phenomena, ISSP, Solubility Phenomena, 13th, Dublin, Ireland, 2008-07-27–2008-07-31

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About the article

Published Online: 2009-08-04

Published in Print: 2009-08-04


Citation Information: Pure and Applied Chemistry, Volume 81, Issue 9, Pages 1547–1553, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/PAC-CON-08-10-21.

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