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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen


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Volume 81, Issue 9

Issues

Solubility and related properties in hydrometallurgy

Erich Königsberger
  • Corresponding author
  • School of Chemical and Mathematical Sciences, Murdoch University, Murdoch, WA 6150, Australia
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Glenn Hefter
  • Corresponding author
  • School of Chemical and Mathematical Sciences, Murdoch University, Murdoch, WA 6150, Australia
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Peter M. May
  • Corresponding author
  • School of Chemical and Mathematical Sciences, Murdoch University, Murdoch, WA 6150, Australia
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2009-08-10 | DOI: https://doi.org/10.1351/PAC-CON-09-01-02

Thermodynamically consistent models based on accurately measured data are required for reliable predictions of equilibria and thermodynamic properties for a wide variety of multicomponent, multiphase systems and reactions relevant to hydrometallurgy. Recent developments in our laboratory concerning the measurement and modeling of physicochemical properties of electrolyte solutions over wide ranges of conditions are reviewed. Particular emphasis is on applications to the refining of alumina via the Bayer process, in which various solubility phenomena involving solid, aqueous, and gaseous phases are of critical importance to product yield and purity as well as to economical and environmental sustainability. Appropriately designed models and software allow these aspects to be tackled by thermodynamic process simulations of alumina refinery circuits.

Keywords: aqueous solutions; density; heat capacity; high pressure; high temperature; modeling; solubility; thermodynamics

Conference

International Symposium on Solubility Phenomena and Related Equilibrium Processes (ISSP-13), International Symposium on Solubility Phenomena, ISSP, Solubility Phenomena, 13th, Dublin, Ireland, 2008-07-27–2008-07-31

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About the article

Published Online: 2009-08-10

Published in Print: 2009-08-10


Citation Information: Pure and Applied Chemistry, Volume 81, Issue 9, Pages 1537–1545, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/PAC-CON-09-01-02.

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