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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen

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Volume 82, Issue 11


Formal Lewis acidic character of gold nanocluster catalyst

Hidehiro Sakurai / Ikuyo Kamiya
  • Corresponding author
  • Research Center for Molecular Scale Nanoscience, Institute for Molecular Science, Myodaiji, Okazaki 444-8787, Japan
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Hiroaki Kitahara
  • Corresponding author
  • School of Physical Science, The Graduate University for Advanced Studies, Myodaiji, Okazaki 444-8787, Japan
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2010-08-01 | DOI: https://doi.org/10.1351/PAC-CON-09-12-06

Gold nanoclusters (NCs) stabilized by the poly(N-vinyl-2-pyrrolidone) hydrophilic polymer (Au:PVP) behave not only as aerobic oxidation catalyst but also formal Lewis acid catalyst, which promotes the intramolecular heterocyclization of γ-hydroxyalkenes and γ-aminoalkenes.

Keywords: aerobic oxidation; gold nanoclusters; heterocyclization; hydroamination; Lewis acid


International Symposium on Novel Materials and Their Synthesis (NMS-V) and the 19th International Symposium on Fine Chemistry and Functional Polymers (FCFP-XIX), Novel Materials and their Synthesis, NMS, Novel Materials and their Synthesis, 5th, Shanghai, China, 2009-10-18–2009-10-22


About the article

Published Online: 2010-08-01

Published in Print: 2010-08-01

Citation Information: Pure and Applied Chemistry, Volume 82, Issue 11, Pages 2005–2016, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/PAC-CON-09-12-06.

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