Jump to ContentJump to Main Navigation
Show Summary Details

Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Weir, Ron / Stohner, Jürgen


IMPACT FACTOR increased in 2015: 2.615
5-year IMPACT FACTOR: 3.127
Rank 60 out of 163 in category Chemistry, Multidisciplinary in the 2015 Thomson Reuters Journal Citation Report/Science Edition

SCImago Journal Rank (SJR) 2014: 1.012
Source Normalized Impact per Paper (SNIP) 2014: 1.187
Impact per Publication (IPP) 2014: 2.785

249,00 € / $374.00 / £187.00*

Online
ISSN
1365-3075
See all formats and pricing

 


Select Volume and Issue

Issues

20,00 € / $25.00 / £15.00

Get Access to Full Text

Synthesis and structure of stable 1,2-diaryldisilyne

Takahiro Sasamori1 / Joon Soo Han1 / Koji Hironaka1 / Nozomi Takagi2 / Shigeru Nagase2 / Norihiro Tokitoh1

1Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan

2Department of Theoretical Molecular Science, Institute for Molecular Science, Myodaiji, Okazaki 444-8585, Japan

Conference

International Conference on Heteroatom Chemistry (ICHAC-9), International Conference on Heteroatom Chemistry, ICHAC, Heteroatom Chemistry, 9th, Oviedo, Spain, 2009-06-30–2009-07-04

Citation Information: Pure and Applied Chemistry. Volume 82, Issue 3, Pages 603–612, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: 10.1351/PAC-CON-09-08-02, February 2010

Publication History

Published Online:
2010-02-24

A novel 1,2-diaryldisilyne, BbtSi≡SiBbt (Bbt = 2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl), was synthesized as a stable compound by reduction of the corresponding 1,2-dibromodisilene, Bbt(Br)Si=Si(Br)Bbt. The spectral and structural features of this first stable 1,2-diaryldisilyne are revealed, and the Si≡Si triple-bond character is evaluated with the aid of detailed theoretical calculations. The triple-bond characters of BbtSi≡SiBbt and BbtGe≡GeBbt are compared based on experimental and theoretical results.

Keywords: dibromodisilene; digermyne; disilyne; kinetic stabilization; triple bond

Citing Articles

Here you can find all Crossref-listed publications in which this article is cited. If you would like to receive automatic email messages as soon as this article is cited in other publications, simply activate the “Citation Alert” on the top of this page.

[1]
Carsten Präsang and David Scheschkewitz
Chem. Soc. Rev., 2016, Volume 45, Number 4, Page 900
[2]
Takahiro Sasamori, Tomohiro Sugahara, Tomohiro Agou, Koh Sugamata, Jing-Dong Guo, Shigeru Nagase, and Norihiro Tokitoh
Chem. Sci., 2015, Volume 6, Number 10, Page 5526
[3]
Miroslav Novák, Marek Bouška, Libor Dostál, Aleš Růžička, Alexander Hoffmann, Sonja Herres-Pawlis, and Roman Jambor
Chemistry - A European Journal, 2015, Volume 21, Number 21, Page 7820
[4]
Takahiro Sasamori, Tomohiro Sugahara, Tomohiro Agou, Jing-Dong Guo, Shigeru Nagase, Rainer Streubel, and Norihiro Tokitoh
Organometallics, 2015, Volume 34, Number 11, Page 2106
[5]
Miroslav Novák, Marek Bouška, Libor Dostál, Aleš Růžička, and Roman Jambor
Organometallics, 2014, Volume 33, Number 23, Page 6778
[6]
Xin Tan, Fengyu Li, and Zhongfang Chen
The Journal of Physical Chemistry C, 2014, Volume 118, Number 45, Page 25825
[7]
Tomohiro Agou, Naoki Hayakawa, Takahiro Sasamori, Tsukasa Matsuo, Daisuke Hashizume, and Norihiro Tokitoh
Chemistry - A European Journal, 2014, Volume 20, Number 30, Page 9246
[9]
Shintaro Ishida, Ryutaro Sugawara, Yoshifumi Misawa, and Takeaki Iwamoto
Angewandte Chemie International Edition, 2013, Volume 52, Number 49, Page 12869
[10]
Takahiro Sasamori and Norihiro Tokitoh
Bulletin of the Chemical Society of Japan, 2013, Volume 86, Number 9, Page 1005
[11]
Matthew Asay and Akira Sekiguchi
Bulletin of the Chemical Society of Japan, 2012, Volume 85, Number 12, Page 1245
[12]
Shigeru Nagase
Pure and Applied Chemistry, 2012, Volume 85, Number 4
[13]
Deepthi Jose and Ayan Datta
The Journal of Physical Chemistry C, 2012, Volume 116, Number 46, Page 24639
[14]
Michael Wagner, Christina Dietz, Stefan Krabbe, Stephan G. Koller, Carsten Strohmann, and Klaus Jurkschat
Inorganic Chemistry, 2012, Volume 51, Number 12, Page 6851
[15]
LiLi Zhao, Fang Huang, Gang Lu, Zhi-Xiang Wang, and Paul von Ragué Schleyer
Journal of the American Chemical Society, 2012, Volume 134, Number 21, Page 8856
[16]
Mark M. Law, Jonathan T. Fraser-Smith, and Carlo U. Perotto
Physical Chemistry Chemical Physics, 2012, Volume 14, Number 19, Page 6922
[17]
Cameron Jones, Simon J. Bonyhady, Nicole Holzmann, Gernot Frenking, and Andreas Stasch
Inorganic Chemistry, 2011, Volume 50, Number 24, Page 12315
[18]
Katsuhiko Takeuchi, Masaaki Ichinohe, and Akira Sekiguchi
Journal of the American Chemical Society, 2011, Volume 133, Number 32, Page 12478
[19]
Po-Chao Wu and Ming-Der Su
Inorganic Chemistry, 2011, Volume 50, Number 14, Page 6814
[20]
Yoshitaka Murata, Masaaki Ichinohe, and Akira Sekiguchi
Journal of the American Chemical Society, 2010, Volume 132, Number 47, Page 16768
[21]
[22]
Katsuhiko Takeuchi, Masaaki Ichinohe, and Akira Sekiguchi
Organometallics, 2011, Volume 30, Number 7, Page 2044
[23]
Joon Soo Han, Takahiro Sasamori, Yoshiyuki Mizuhata, and Norihiro Tokitoh
Dalton Transactions, 2010, Volume 39, Number 39, Page 9238

Comments (0)

Please log in or register to comment.