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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen

12 Issues per year


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1365-3075
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Volume 82, Issue 7

Issues

Aerobic oxidation with bifunctional molecular catalysts

Takao Ikariya
  • Corresponding author
  • Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, O-okayama 2-12-1-E4-1, Meguro-ku, Tokyo 152-8552, Japan
  • Other articles by this author:
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/ Shigeki Kuwata
  • Corresponding author
  • Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, O-okayama 2-12-1-E4-1, Meguro-ku, Tokyo 152-8552, Japan
  • Other articles by this author:
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/ Yoshihito Kayaki
  • Corresponding author
  • Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, O-okayama 2-12-1-E4-1, Meguro-ku, Tokyo 152-8552, Japan
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2010-05-04 | DOI: https://doi.org/10.1351/PAC-CON-09-09-11

A new series of half-sandwich group 8 and 9 metal complexes bearing a metal/NH bifunctional moiety were synthesized from benzylic amines. The isolable Ir amide complexes serve as effective catalysts for aerobic oxidative transformation of secondary and primary alcohols into the corresponding ketones and esters under mild conditions. The aerobic oxidative kinetic resolution of racemic secondary alcohols with chiral bifunctional Ir catalysts was found to proceed smoothly under mild conditions with high selectivity. A novel imido-bridged dirhodium complex, which may be regarded as a dinuclear variant of the bifunctional mononuclear amide complexes, also proved to promote aerobic oxidation of a secondary alcohol and H2.

Keywords: aerobic oxidation; alcohol oxidation; bifunctional catalysis; cooperating ligand; H2 oxidation; molecular catalysts

Conference

International Conference on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS-15), International Symposium on Organometallic Chemistry Directed Toward Organic Synthesis, OMCOS, Organometallic Chemistry Directed Toward Organic Synthesis, 15th, Glasgow, UK, 2009-07-26–2009-07-31

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About the article

Published Online: 2010-05-04

Published in Print: 2010-05-04


Citation Information: Pure and Applied Chemistry, Volume 82, Issue 7, Pages 1471–1483, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/PAC-CON-09-09-11.

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