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Pure and Applied Chemistry

The Scientific Journal of IUPAC

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Volume 83, Issue 1 (Nov 2010)


Toward carbon dioxide capture using nanoporous materials

Deanna M. D'Alessandro
  • Corresponding author
  • School of Chemistry, The University of Sydney, Sydney, New South Wales 2006, Australia
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Thomas McDonald
  • Corresponding author
  • Department of Chemistry, University of California, Berkeley, CA 94720-1460, USA
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2010-11-19 | DOI: https://doi.org/10.1351/PAC-CON-10-09-18

The development of more efficient processes for CO2 capture from the flue streams of power plants is considered a key to the reduction of greenhouse gas emissions implicated in global warming. Indeed, several U.S. and international climate change initiatives have identified the urgent need for improved materials and methods for CO2 capture. Conventional CO2 capture processes employed in power plants world-wide are typically postcombustion “wet scrubbing” methods involving the absorption of CO2 by amine-containing solvents such as methanolamine (MEA). These present several disadvantages, including the considerable heat required in regeneration of the solvent and the necessary use of inhibitors for corrosion control, which lead to reduced efficiencies and increased costs for electricity production. This perspective article seeks to highlight the most recent advances in new materials for CO2 capture from power plant flue streams, with particular emphasis on the rapidly expanding field of metal–organic frameworks. Ultimately, the development of new classes of efficient, cost-effective, and industrially viable capture materials for application in carbon capture and storage (CCS) systems offers an immense opportunity to reduce atmospheric emissions of greenhouse gases on a national and international scale.

Keywords: adsorbent materials; carbon dioxide capture; gas separations; metal–organic frameworks; porous coordination polymers


  • 1

    , A. P. Sokolov, P. H. Stone, C. E. Forest, R. Prinn, M. C. Sarofim, M. Webster, S. Paltsev, C. A. Schlosser, D. Kicklighter, S. Dutkiewicz, J. M. Reilly, C. Wang, B. Felzer, H. D. Jacoby. J. Climate 22, 5175 (2009).CrossrefGoogle Scholar

  • 2

    A. Neftel, H. Friedli, E. Moor, H. Lötscher, H. Oeschger, U. Siegenthaler, B. Stauffer. In Trends: A Compendium of Data on Global Change, Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, U.S. Department of Energy (1994).Google Scholar

  • 3

    R. F. Keeling, S. C. Piper, A. F. Bollenbacher, S. J. Walker. In Atmospheric CO2values derived from in situ air samples collected at Manua Loa, Hawaii, USA, Scripps Institution of Oceanography, La Jolla, CA (2009).Google Scholar

  • 4

    U.S. Energy Information Administration. International Energy Outlook 2010, <http:/www.eia.doe.gov/oiaf/ieo/> (2010).Google Scholar

  • 5

    B. Metz, O. Davidson, H. de Coninck, M. Loos, L. Meyer. IPCC Special Report on Carbon Dioxide Capture and Storage. Cambridge University Press, Cambridge, UK (2005).Google Scholar

  • 6

    United Nations Framework Convention on Climate Change. <http:unfccc.int/2860.php>.Google Scholar

  • 7

    Carbon Sequestration Leadership Forum. <http://www.cslforum.org>.Google Scholar

  • 8

    Global Climate Change Initiative. <http://www.state.gov/g/oes/rls/fs/2002/12956.htm>.Google Scholar

  • 9

    FutureGen Alliance, Inc. <http://www.futuregenalliance.org>.Google Scholar

  • 10

    , C. E. Powell, G. G. Qiao. J. Membr. Sci. 279, 1 (2006).CrossrefGoogle Scholar

  • 11

    , J. D. Figueroa, T. Fout, S. Plasynski, H. McIlvried, R. D. Srivastava. Int. J. Greenhouse Gas Control 2, 9 (2008).CrossrefGoogle Scholar

  • 12

    , S. Freguia, G. T. Rochelle. AIChE J. 49, 1676 (2003).CrossrefGoogle Scholar

  • 13

    , P. D. Vaidya, E. Y. Kenig. Chem. Eng. Technol. 30, 1467 (2007).CrossrefGoogle Scholar

  • 14

    , P. H. M. Feron, C. A. Hendriks. Oil Gas Sci. Technol. 60, 451 (2005).CrossrefGoogle Scholar

  • 15

    , L. I. Eide, D. W. Bailey. Oil Gas Sci. Technol. 60, 475 (2005).CrossrefGoogle Scholar

  • 16

    , M. M. Abu-Khader. Energy Sources, Part A 28, 1261 (2006).CrossrefGoogle Scholar

  • 17

    , D. M. D’Alessandro, B. Smit, J. R. Long. Angew. Chem., Int. Ed. 49, 6058 (2010).CrossrefGoogle Scholar

  • 18

    S. Shackley, C. Gough (Eds.). Carbon Capture and its Storage: An Integrated Assessment, Ashgate, UK (2006).Google Scholar

  • 19

    , X. Xu, C. Song, B. G. Miller, A. W. Scaroni. Fuel Process. Technol. 86, 1457 (2005).CrossrefGoogle Scholar

  • 20

    , J. C. Hicks, J. H. Drese, D. J. Fauth, M. L. Gray, G. Qi, C. W. Jones. J. Am. Chem. Soc. 130, 2902 (2008).CrossrefGoogle Scholar

  • 21

    , O. Leal, C. Bolivar, C. Ovalles, J. Garcia, Y. Espidel. Inorg. Chim. Acta 240, 183 (1995).CrossrefGoogle Scholar

  • 22

    R. V. Sirwardane. 6,908,497 B1 (2005).Google Scholar

  • 23

    , P. J. E. Harlick, F. H. Tezel. Microporous Mesoporous Mater. 76, 71 (2004).CrossrefGoogle Scholar

  • 24

    , G. Maurin, P. L. Llewellyn, R. G. Bell. J. Phys. Chem. B 109, 16084 (2005).CrossrefGoogle Scholar

  • 25

    , R. Banerjee, A. Phan, B. Wang, C. Knobler, H. Furukawa, M. O’Keeffe, O. M. Yaghi. Science 319, 939 (2008).CrossrefGoogle Scholar

  • 26

    , K. S. Park, Z. Ni, A. P. Cote, J. Y. Choi, R. Huang, F. J. Uribe-Romo, H. K. Chae, M. O’Keeffe, O. M. Yaghi. Proc. Nat. Acad. Sci. USA 103, 10186 (2006).CrossrefGoogle Scholar

  • 27

    , H. Hayashi, A. P. Cote, H. Furukawa, M. O’Keeffe, O. M. Yaghi. Nat. Mater. 6, 501 (2007).CrossrefGoogle Scholar

  • 28

    X.-J. Hou, H. Li. J. Phys. Chem. C 114, 13501 (2010).Google Scholar

  • 29

    , W. Morris, B. Leung, H. Furukawa, O. K. Yaghi, N. He, H. Hayashi, Y. Houndonougbo, M. Asta, B. B. Laird, O. M. Yaghi. J. Am. Chem. Soc. 132, 11006 (2010).CrossrefGoogle Scholar

  • 30

    , L. Schlapbach, A. Züttel. Nature 414, 353 (2001).CrossrefGoogle Scholar

  • 31

    , O. M. Yaghi, M. O’Keeffe, N. W. Ockwig, H. K. Chae, M. Eddaoudi, J. Kim. Nature 423, 705 (2003).CrossrefGoogle Scholar

  • 32

    , U. Mueller, M. Schubert, F. Teich, H. Puetter, K. Schierle-Arndt, J. Pastre. J. Mater. Chem. 16, 626 (2006).CrossrefGoogle Scholar

  • 33

    , N. L. Rosi, J. Eckert, M. Eddaoudi, D. T. Vodak, J. Kim, M. O’Keeffe, O. M. Yaghi. Science 300, 1127 (2003).CrossrefGoogle Scholar

  • 34

    , D. J. Collins, H.-C. Zhou. J. Mater. Chem. 17, 3154 (2007).CrossrefGoogle Scholar

  • 35

    L. J. Murray, M. Dincă, J. Long. Chem. Soc. Rev. 39, 1294 (2008).Google Scholar

  • 36

    Z. Xiang, D. Cao, X. Shao, W. Wang, J. Zhang, W. Wu. Chem. Eng. Sci. 65, 3140 (2010).Google Scholar

  • 37

    , O. K. Farha, J. T. Hupp. Acc. Chem. Res. 43, 1166 (2010).CrossrefGoogle Scholar

  • 38

    , K. Sumida, S. Horike, S. S. Kaye, Z. R. Herm, W. L. Queen, C. M. Brown, F. Grandjean, G. J. Long, A. Dailly, J. R. Long. Chem. Sci. 1, 184 (2010).CrossrefGoogle Scholar

  • 39

    , A. R. Millward, O. M. Yaghi. J. Am. Chem. Soc. 127, 17998 (2005).CrossrefGoogle Scholar

  • 40

    , H. Furukawa, N. Ko, Y. B. Go, N. Aratani, S. B. Choi, E. Choi, A. O. Yazaydin, R. Q. Snurr, M. O’Keeffe, J. Kim, O. Yaghi. Science 329, 424 (2010).CrossrefGoogle Scholar

  • 41

    , N. A. Ramsahye, G. Maurin, S. Bourrelly, P. L. Llewellyn, C. Serre, T. Loiseau, T. Devic, G. Ferey. J. Phys. Chem. C 112, 514 (2008).CrossrefGoogle Scholar

  • 42

    , C. Serre, S. Bourrelly, A. Vimont, N. A. Ramsahye, G. Maurin, P. L. Llewellyn, M. Daturi, Y. Filinchuk, O. Leynaud, P. Barnes, G. Ferey. Adv. Mater. 19, 2246 (2007).CrossrefGoogle Scholar

  • 43

    , N. A. Ramsahye, G. Maurin, S. Bourrelly, P. L. Llewellyn, T. Loiseau, C. Serre, G. Ferey. Chem. Commun. 3261 (2007).CrossrefGoogle Scholar

  • 44

    , N. A. Ramsahye, G. Maurin, S. Bourrelly, P. Llewellyn, T. Loiseau, G. Ferey. Phys. Chem. Chem. Phys. 9, 1059 (2007).CrossrefGoogle Scholar

  • 45

    , P. L. Llewellyn, S. Bourrrelly, C. Serre, Y. Filinchuk, G. Ferey. Angew. Chem., Int. Ed. 45, 7751 (2006).CrossrefGoogle Scholar

  • 46

    , A. R. Millward, O. M. Yaghi. J. Am. Chem. Soc. 127, 17998 (2005).CrossrefGoogle Scholar

  • 47

    , A. Demessence, D. M. D’Alessandro, M. L. Foo, J. R. Long. J. Am. Chem. Soc. 131, 8784 (2009).CrossrefGoogle Scholar

  • 48

    , J.-M. Gu, T.-H. Kwon, J.-H. Park, S. Huh. Dalton Trans. 39, 5608 (2010).CrossrefGoogle Scholar

  • 49

    , J. An, N. Rosi. J. Am. Chem. Soc. 132, 5578 (2010).CrossrefGoogle Scholar

  • 50

    , A. Torrisi, R. G. Bell, C. Mellot-Draznieks. Cryst. Growth Des. 10, 2839 (2010).CrossrefGoogle Scholar

  • 51

    , R. Babarao, J. W. Jiang. Ind. Eng. Chem. Res. (2010).CrossrefGoogle Scholar

  • 52

    , J. Lan, D. Cao, W. Wang, B. Smit. ACS Nano 4, 4225 (2010).CrossrefGoogle Scholar

  • 53

    , R. Babarao, J. W. Jiang. Energy Environ. Sci. 2, 1088 (2009).CrossrefGoogle Scholar

  • 54

    , R. Babarao, M. Eddaoudi, J. W. Jiang. Langmuir 26, 11196 (2010).CrossrefGoogle Scholar

  • 55

    , J. Liu, Y. Wang, A. I. Benin, P. Jakubezak, R. R. Willis, M. D. LeVan. Langmuir 26, 14301 (2010).CrossrefGoogle Scholar

About the article

Published Online: 2010-11-19

Published in Print: 2010-11-19

Citation Information: Pure and Applied Chemistry, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/PAC-CON-10-09-18.

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