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Pure and Applied Chemistry

The Scientific Journal of IUPAC

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Volume 83, Issue 10

Issues

Definitions of terms relating to crystalline polymers (IUPAC Recommendations 2011)

Stefano V. Meille
  • Corresponding author
  • Dipartimento di Chimica, Materiali e Ingegneria Chimica, “G. Natta”, Politecnico di Milano, Via L. Mancinelli, 7, 20131 Milano, Italy
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/ Giuseppe Allegra
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  • Dipartimento di Chimica, Materiali e Ingegneria Chimica, “G. Natta”, Politecnico di Milano, Via L. Mancinelli, 7, 20131 Milano, Italy
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/ Phillip H. Geil
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  • Department of Materials Science and Engineering, University of Illinois, 1304 W. Green St., Urbana, IL 61801, USA
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/ Jiasong He
  • Corresponding author
  • Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
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/ Michael Hess
  • Corresponding author
  • Makromolekulare Chemie Universität-Gesamthochschule Siegen, Adolf-Reichwein-Strasse, D-57068 Siegen, Germany
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/ Jung-Il Jin
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  • Department of Chemistry, Korea University, College of Sciences, 5-1 Anam Dong, Sungbuk-ku, Seoul 136-701, Korea
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/ Pavel Kratochvíl
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  • Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Heyrovský Sq. 2, 162 06 Praha 6, Czech Republic
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/ Werner Mormann
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  • Makromolekulare Chemie Universität-Gesamthochschule Siegen, Adolf-Reichwein-Strasse, D-57068 Siegen, Germany
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/ Robert Stepto
Published Online: 2011-08-03 | DOI: https://doi.org/10.1351/PAC-REC-10-11-13

Recommendations are given concerning the terminology relating to the structure and the morphology of crystalline polymers and the processes of polymer crystallization. They are applicable to cases where polymer crystals are a significant fraction of a system and primarily with crystal structures that are comprised of polymer chains with limited, static, or dynamic disorder. After some general definitions, terms pertaining to structural arrangements at subnanometric scales and to polymer crystal structures are defined. Terms relating to molecular conformation within polymer crystals, morphological aspects, and polymer crystallization are given in subsequent sections.

Keywords: crystalline polymer conformation; crystalline polymers; IUPAC Polymer Division; morphology; polymer crystallization; polymer crystal structure

Project Year: 2003, Project Code: 2003-019-2-400

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About the article

Published Online: 2011-08-03

Published in Print: 2011-08-03


Citation Information: Pure and Applied Chemistry, Volume 83, Issue 10, Pages 1831–1871, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/PAC-REC-10-11-13.

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