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Pure and Applied Chemistry

The Scientific Journal of IUPAC

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Volume 83, Issue 12 (Aug 2011)

Issues

Standards for photoluminescence quantum yield measurements in solution (IUPAC Technical Report)

Albert M. Brouwer
  • Corresponding author
  • Universiteit van Amsterdam, P.O. Box 94157, 1090 GD Amsterdam, The Netherlands
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2011-08-31 | DOI: https://doi.org/10.1351/PAC-REP-10-09-31

The use of standards for the measurement of photoluminescence quantum yields (QYs) in dilute solutions is reviewed. Only three standards can be considered well established. Another group of six standards has been investigated by several independent researchers. A large group of standards is frequently used in recent literature, but the validity of these is less certain. The needs for future development comprise: (i) confirmation of the validity of the QY values of many commonly used standard materials, preferably in the form of SI traceable standards; (ii) extension of the set of standard materials to the UV and near-IR spectral ranges; and (iii) good standards or robust protocols for the measurements of low QYs.

Keywords: IUPAC Analytical Chemistry Division; IUPAC Organic and Biomolecular Chemistry Division; IUPAC Physical and Biophysical Chemistry Division; measurements in solution; photoluminescence; photons; quantum yield; standards

Project Year: 2004, Project Code: 2004-021-1-300

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About the article

Published Online: 2011-08-31

Published in Print: 2011-08-31


Citation Information: Pure and Applied Chemistry, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/PAC-REP-10-09-31.

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