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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen


IMPACT FACTOR 2018: 2.350
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1365-3075
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Volume 83, Issue 8

Issues

Superelectrophilic chemistry in the gas phase

Jana Roithová
  • Corresponding author
  • Department of Organic and Nuclear Chemistry, Faculty of Science, Charles University in Prague, Hlavova 2030, 128 43 Prague 2, Czech Republic
  • Other articles by this author:
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Published Online: 2011-04-04 | DOI: https://doi.org/10.1351/PAC-CON-10-10-17

Superelectrophilic chemistry in the gas phase is driven by the high intrinsic reactivity of dications. The formation of new doubly charged products proceeds via highly internally excited intermediates. Conditions for the formation of the doubly charged intermediates and a “cooling principle” in the reactivity of dications are explained. The reactivity is demonstrated with several examples.

Keywords: dications; gas phase; ionization; mass spectrometry; superelectrophiles

Conference

International Conference on Physical Organic Chemistry (ICPOC-20), International Conference on Physical Organic Chemistry, ICPOC, Physical Organic Chemistry, 20th, Busan, Korea, 2010-08-22–2010-08-27

References

About the article

Published Online: 2011-04-04

Published in Print: 2011-04-04


Citation Information: Pure and Applied Chemistry, Volume 83, Issue 8, Pages 1499–1506, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/PAC-CON-10-10-17.

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[1]
Guilherme L. Tripodi, Thiago C. Correra, Célio F. F. Angolini, Bruno R. V. Ferreira, Philippe Maître, Marcos N. Eberlin, and Jana Roithová
European Journal of Organic Chemistry, 2019, Volume 2019, Number 22, Page 3560
[2]
Detlef Schröder
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[3]
Luiz Alberto Beraldo Moraes, Eduardo César Meurer, and Marcos Nogueira Eberlin
International Journal of Mass Spectrometry, 2017
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Markus Rohdenburg, Martin Mayer, Max Grellmann, Carsten Jenne, Tobias Borrmann, Florian Kleemiss, Vladimir A. Azov, Knut R. Asmis, Simon Grabowsky, and Jonas Warneke
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[5]
Markus Rohdenburg, Martin Mayer, Max Grellmann, Carsten Jenne, Tobias Borrmann, Florian Kleemiss, Vladimir A. Azov, Knut R. Asmis, Simon Grabowsky, and Jonas Warneke
Angewandte Chemie International Edition, 2017, Volume 56, Number 27, Page 7980
[6]
Juraj Jašík and Jana Roithová
International Journal of Mass Spectrometry, 2015, Volume 377, Page 109
[7]
Juraj Jašík, Ján Žabka, Jana Roithová, and Dieter Gerlich
International Journal of Mass Spectrometry, 2013, Volume 354-355, Page 204
[8]
Christopher J. Shaffer, Detlef Schröder, Jana Roithová, Emilie-Laure Zins, Christian Alcaraz, Jan Žabka, Miroslav Polášek, and Daniela Ascenzi
International Journal of Mass Spectrometry, 2013, Volume 336, Page 17
[9]
Christopher J. Shaffer, Detlef Schröder, Christian Alcaraz, Ján Žabka, and Emilie-Laure Zins
ChemPhysChem, 2012, Volume 13, Number 11, Page 2688
[10]
Lauren Levee, Catherine Calogero, Edward Barbieri, Steven Byrne, Courtney Donahue, Michael Eisenberg, Sean Hattenbach, Julie Le, Joseph F. Capitani, Jana Roithová, and Detlef Schröder
International Journal of Mass Spectrometry, 2012, Volume 323-324, Page 2
[11]
Jana Roithova
ChemInform, 2012, Volume 43, Number 24, Page no
[12]
Christopher Shaffer, Detlef Schröder, Emilie-Laure Zins, Christian Alcaraz, Jan Žabka, and Jana Roithová
Chemical Physics Letters, 2012, Volume 534, Page 8
[13]
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International Journal of Mass Spectrometry, 2012, Volume 311, Page 51

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