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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen

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Volume 84, Issue 7

Issues

Spiroketals: Toward the synthesis of 39-oxobistramide K

Malgorzata Commandeur
  • Corresponding author
  • Laboratoire de Chimie Organique Associé au CNRS, ESPCI ParisTech, 10 rue Vauquelin, 75231 Paris Cedex 05, France
  • Other articles by this author:
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/ Claude Commandeur
  • Corresponding author
  • Laboratoire de Chimie Organique Associé au CNRS, ESPCI ParisTech, 10 rue Vauquelin, 75231 Paris Cedex 05, France
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Janine Cossy
  • Corresponding author
  • Laboratoire de Chimie Organique Associé au CNRS, ESPCI ParisTech, 10 rue Vauquelin, 75231 Paris Cedex 05, France
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2012-02-28 | DOI: https://doi.org/10.1351/PAC-CON-11-09-06

An advanced spiroketal intermediate toward the synthesis of 39-oxobistramide K was prepared, fragment C14–C40. This fragment was obtained in 19 steps with an overall yield of 6.2 % using a FeCl3-catalyzed spiroketalization as the key step.

Keywords: cyclizations; organic synthesis; spiroketalization

Conference

International Conference on Heterocyclic Chemistry (ICHC-23), International Congress on Heterocyclic Chemistry, ICHC, Heterocyclic Chemistry, 23rd, Glasgow, UK, 2011-07-31–2011-08-04

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About the article

Published Online: 2012-02-28

Published in Print: 2012-02-29


Citation Information: Pure and Applied Chemistry, Volume 84, Issue 7, Pages 1567–1574, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/PAC-CON-11-09-06.

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