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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen


IMPACT FACTOR 2017: 5.294

CiteScore 2017: 3.42

SCImago Journal Rank (SJR) 2017: 1.212
Source Normalized Impact per Paper (SNIP) 2017: 1.546

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1365-3075
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Volume 85, Issue 2

Issues

Lower- and upper-rim-modified derivatives of 1,3,5-triaza-7-phosphaadamantane: Coordination chemistry and applications in catalytic reactions in water

Luca Gonsalvi
  • Corresponding author
  • Consiglio Nazionale delle Ricerche, Istituto di Chimica dei Composti Organometallici (ICCOM-CNR), Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze), Italy
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Antonella Guerriero
  • Corresponding author
  • Consiglio Nazionale delle Ricerche, Istituto di Chimica dei Composti Organometallici (ICCOM-CNR), Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze), Italy
  • Other articles by this author:
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/ Frédéric Hapiot
  • Corresponding author
  • Université Lille Nord de France, CNRS UMR 8181, Unité de Catalyse et de Chimie du Solide, UCCS UArtois, Faculté Jean Perrin, rue Jean Souvraz, SP18, F-62300 Lens, France
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Donald A. Krogstad / Eric Monflier
  • Corresponding author
  • Université Lille Nord de France, CNRS UMR 8181, Unité de Catalyse et de Chimie du Solide, UCCS UArtois, Faculté Jean Perrin, rue Jean Souvraz, SP18, F-62300 Lens, France
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Gianna Reginato
  • Corresponding author
  • Consiglio Nazionale delle Ricerche, Istituto di Chimica dei Composti Organometallici (ICCOM-CNR), Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze), Italy
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Maurizio Peruzzini
  • Corresponding author
  • Consiglio Nazionale delle Ricerche, Istituto di Chimica dei Composti Organometallici (ICCOM-CNR), Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze), Italy
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2012-11-17 | DOI: https://doi.org/10.1351/PAC-CON-12-07-10

In this article, a brief review of the recent functionalizations of the cage-like water-soluble phosphine 1,3,5-triaza-7-phosphaadamantane (PTA), involving N-quaternization (lower rim) and introduction of a side arm in C-6 position (upper rim) will be presented, highlighting selected examples in their use as ligands for ruthenium(II), iridium(I), and rhodium(I) moieties together with applications of the related complexes in homogeneous catalysis.

Keywords: homogeneous catalysis; hydroformylation; hydrogenation; organometallic chemistry; transition metals; water

Conference

Eurasia Conference on Chemical Sciences, 12th, Corfu, Greece, 2012-04-16–2012-04-21

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About the article

Published Online: 2012-11-17

Published in Print: 2012-11-17


Citation Information: Pure and Applied Chemistry, Volume 85, Issue 2, Pages 385–396, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/PAC-CON-12-07-10.

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