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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen

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Volume 85, Issue 4


Multiple bonds between lead atoms and short bonds between transition metals

Shigeru Nagase
  • Corresponding author
  • Fukui Institute for Fundamental Chemistry, Kyoto University, Takano-nishihiraki-cho 34-3, Sakyo-ku, Kyoto 606-8103, Japan
  • Other articles by this author:
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Published Online: 2012-12-29 | DOI: https://doi.org/10.1351/PAC-CON-12-08-04

The heaviest analogues of alkynes are investigated to realize a short triple bond between Pb atoms. For a short double bond between Pb atoms, the Pb2 molecule stabilized by dative N-heterocyclic carbenes is investigated. For unsupported and supported short bonds between transition metals, two-coordinate transition-metal and bicyclic four-membered ring complexes are investigated.

Keywords: alkynes; computational chemistry; main-group atoms; multiple bonds; organometallic chemistry; short bonds; transition metals


International Conference on Heteroatom Chemistry (ICHAC-10), International Conference on Heteroatom Chemistry, ICHAC, Heteroatom Chemistry, 10th, Kyoto, Japan, 2012-05-20–2012-05-25


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About the article

Published Online: 2012-12-29

Published in Print: 2012-12-31

Citation Information: Pure and Applied Chemistry, Volume 85, Issue 4, Pages 649–659, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/PAC-CON-12-08-04.

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