Jump to ContentJump to Main Navigation
Show Summary Details
More options …

Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen


IMPACT FACTOR 2018: 2.350
5-year IMPACT FACTOR: 4.037

CiteScore 2018: 4.66

SCImago Journal Rank (SJR) 2018: 1.240
Source Normalized Impact per Paper (SNIP) 2018: 1.826

Online
ISSN
1365-3075
See all formats and pricing
More options …
Volume 85, Issue 8

Issues

Effective synthesis of cyclic carbonates from CO2 and epoxides catalyzed by KI/cucurbit[6]uril

Jinghua Shi
  • Corresponding author
  • Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Jinliang Song
  • Corresponding author
  • Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Jun Ma
  • Corresponding author
  • Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Zhaofu Zhang
  • Corresponding author
  • Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Honglei Fan
  • Corresponding author
  • Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Buxing Han
  • Corresponding author
  • Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2013-04-04 | DOI: https://doi.org/10.1351/PAC-CON-12-10-09

The development of efficient, inexpensive, and nontoxic catalysts for cycloaddition of CO2 with epoxides to produce five-membered cyclic carbonates is a very interesting topic. In this work, cycloaddition of CO2 with propylene oxide (PO) to produce propylene carbonate (PC) catalyzed by potassium halides (KCl, KBr, and KI) in the presence of cucurbit[6]uril (CB[6]) was studied at various conditions. It was discovered that the potassium halides and CB[6] had excellent synergetic effect in promoting the reaction, and the KI/CB[6] catalytic system was the most efficient among them. The decrease of the activity and selectivity of KI/CB[6] was negligible after the catalytic system was reused five times. Further study indicated that the KI/CB[6] catalytic system was also very active and selective for the cycloaddition of CO2 with other epoxides, such as glycidyl phenyl ether, epichlorohydrin, and styrene oxide. The mechanism for the synergetic effect of KI and CB[6] was also discussed.

Keywords: cucurbit[6]uril; cyclic carbonates; cycloadditions; potassium halides; synergetic effects

Conference

International Conference on Green Chemistry (ICGC-4), IUPAC International Conference on Green Chemistry, ICGC, Green Chemistry , 4th, Foz do Iguaçu, Brazil, 2012-08-25–2012-08-29

References

About the article

Published Online: 2013-04-04

Published in Print: 2013-04-04


Citation Information: Pure and Applied Chemistry, Volume 85, Issue 8, Pages 1633–1641, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/PAC-CON-12-10-09.

Export Citation

© 2013 Walter de Gruyter GmbH, Berlin/Boston.Get Permission

Citing Articles

Here you can find all Crossref-listed publications in which this article is cited. If you would like to receive automatic email messages as soon as this article is cited in other publications, simply activate the “Citation Alert” on the top of this page.

[1]
Yan-Li Shi, Peng Zhang, Ding-Hua Liu, Peng-Fei Zhou, and Lin-Bing Sun
Catalysis Letters, 2015, Volume 145, Number 9, Page 1673
[2]
Takumi Nakamura, Megumi Okada, and Seiji Shirakawa
Journal of Synthetic Organic Chemistry, Japan, 2019, Volume 77, Number 8, Page 791
[3]
Yuya Hu, Johannes Steinbauer, Vivian Stefanow, Anke Spannenberg, and Thomas Werner
ACS Sustainable Chemistry & Engineering, 2019, Volume 7, Number 15, Page 13257
[4]
Qingshuo Li, Haibo Chang, Runming Li, Hongxia Wang, Jichun Liu, Shanhu Liu, Congzhen Qiao, and Tong Lin
Molecular Catalysis, 2019, Volume 469, Page 111
[5]
Dongwoo Kim, Hoon Ji, Moon Young Hur, Wonjoo Lee, Tea Soon Kim, and Deug-Hee Cho
ACS Sustainable Chemistry & Engineering, 2018
[6]
Chihiro Maeda, Sota Sasaki, Kazuto Takaishi, and Tadashi Ema
Catalysis Science & Technology, 2018
[7]
Shuang Yue, Qian Song, Shuliang Zang, Guichun Deng, and Jun Li
Australian Journal of Chemistry, 2018, Volume 71, Number 6, Page 407
[8]
Megumi Okada, Ryuichi Nishiyori, Shiho Kaneko, Kazunobu Igawa, and Seiji Shirakawa
European Journal of Organic Chemistry, 2018, Volume 2018, Number 17, Page 2022
[9]
Haibo Chang, Qingshuo Li, Xuemin Cui, Hongxia Wang, Congzhen Qiao, Zhanwei Bu, and Tong Lin
Molecular Catalysis, 2018, Volume 449, Page 25
[10]
Haibo Chang, Qingshuo Li, Xuemin Cui, Hongxia Wang, Zhanwei Bu, Congzhen Qiao, and Tong Lin
Journal of CO2 Utilization, 2018, Volume 24, Page 174
[11]
Liangzheng Ji, Zhoujie Luo, Yongya Zhang, Rong Wang, Yayan Ji, Fei Xia, and Guohua Gao
Molecular Catalysis, 2018, Volume 446, Page 124
[12]
M. Alves, B. Grignard, R. Mereau, C. Jerome, T. Tassaing, and C. Detrembleur
Catal. Sci. Technol., 2017, Volume 7, Number 13, Page 2651
[13]
Shiho Kaneko and Seiji Shirakawa
ACS Sustainable Chemistry & Engineering, 2017, Volume 5, Number 4, Page 2836
[14]
Dongwoo Kim, Yeji Moon, Dahye Ji, Hyeongook Kim, and Deughee Cho
ACS Sustainable Chemistry & Engineering, 2016, Volume 4, Number 9, Page 4591
[15]
Willi Desens, Christina Kohrt, Marcus Frank, and Thomas Werner
ChemSusChem, 2015, Volume 8, Number 22, Page 3815
[16]
James W. Comerford, Ian D. V. Ingram, Michael North, and Xiao Wu
Green Chem., 2015, Volume 17, Number 4, Page 1966
[17]
Jose Tharun, Kuruppathparambil Roshith Roshan, Amal Cherian Kathalikkattil, Dong-Heon Kang, Hyun-Mo Ryu, and Dae-Won Park
RSC Adv., 2014, Volume 4, Number 78, Page 41266
[18]
Kuruppathparambil Roshith Roshan, Tharun Jose, Dongwoo Kim, Kathalikkattil Amal Cherian, and Dae Won Park
Catal. Sci. Technol., 2014, Volume 4, Number 4, Page 963
[19]
Kuruppathparambil Roshith Roshan, Amal Cherian Kathalikkattil, Jose Tharun, Dong Woo Kim, Yong Sun Won, and Dae Won Park
Dalton Trans., 2014, Volume 43, Number 5, Page 2023
[20]
Subodh Kumar and Suman L. Jain
Industrial & Engineering Chemistry Research, 2014, Volume 53, Number 2, Page 541

Comments (0)

Please log in or register to comment.
Log in