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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen


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Volume 85, Issue 8

Issues

Cellulose recycling as a source of raw chirality

Valeria Corne
  • Corresponding author
  • Instituto de Química Rosario, Facultad de Ciencias Bioquímicas y Farmacéuticas, Universidad Nacional de Rosario – CONICET, Suipacha 531, S2002LRK, Rosario, Argentina
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/ María Celeste Botta
  • Corresponding author
  • Instituto de Química Rosario, Facultad de Ciencias Bioquímicas y Farmacéuticas, Universidad Nacional de Rosario – CONICET, Suipacha 531, S2002LRK, Rosario, Argentina
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/ Enrique D. V. Giordano
  • Corresponding author
  • Instituto de Química Rosario, Facultad de Ciencias Bioquímicas y Farmacéuticas, Universidad Nacional de Rosario – CONICET, Suipacha 531, S2002LRK, Rosario, Argentina
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/ Germán F. Giri
  • Corresponding author
  • Instituto de Química Rosario, Facultad de Ciencias Bioquímicas y Farmacéuticas, Universidad Nacional de Rosario – CONICET, Suipacha 531, S2002LRK, Rosario, Argentina
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/ David F. Llompart
  • Corresponding author
  • Instituto de Química Rosario, Facultad de Ciencias Bioquímicas y Farmacéuticas, Universidad Nacional de Rosario – CONICET, Suipacha 531, S2002LRK, Rosario, Argentina
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/ Hernán D. Biava
  • Corresponding author
  • Instituto de Química Rosario, Facultad de Ciencias Bioquímicas y Farmacéuticas, Universidad Nacional de Rosario – CONICET, Suipacha 531, S2002LRK, Rosario, Argentina
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/ Ariel M. Sarotti
  • Corresponding author
  • Instituto de Química Rosario, Facultad de Ciencias Bioquímicas y Farmacéuticas, Universidad Nacional de Rosario – CONICET, Suipacha 531, S2002LRK, Rosario, Argentina
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/ María I. Mangione
  • Corresponding author
  • Instituto de Química Rosario, Facultad de Ciencias Bioquímicas y Farmacéuticas, Universidad Nacional de Rosario – CONICET, Suipacha 531, S2002LRK, Rosario, Argentina
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/ Ernesto G. Mata
  • Corresponding author
  • Instituto de Química Rosario, Facultad de Ciencias Bioquímicas y Farmacéuticas, Universidad Nacional de Rosario – CONICET, Suipacha 531, S2002LRK, Rosario, Argentina
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/ Alejandra G. Suárez
  • Corresponding author
  • Instituto de Química Rosario, Facultad de Ciencias Bioquímicas y Farmacéuticas, Universidad Nacional de Rosario – CONICET, Suipacha 531, S2002LRK, Rosario, Argentina
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/ Rolando A. Spanevello
  • Corresponding author
  • Instituto de Química Rosario, Facultad de Ciencias Bioquímicas y Farmacéuticas, Universidad Nacional de Rosario – CONICET, Suipacha 531, S2002LRK, Rosario, Argentina
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Published Online: 2013-07-10 | DOI: https://doi.org/10.1351/PAC-CON-12-11-10

Modern organic chemistry requires easily obtainable chiral building blocks that show high chemical versatility for their application in the synthesis of enantiopure compounds. Biomass has been demonstrated to be a widely available raw material that represents the only abundant source of renewable organic carbon. Through the pyrolitic conversion of cellulose or cellulose-containing materials it is possible to produce levoglucosenone, a highly functionalized chiral structure. This compound has been innovatively used as a template for the synthesis of key intermediates of biologically active products and for the preparation of chiral auxiliaries, catalysts, and organocatalysts for their application in asymmetric synthesis.

Keywords: asymmetric synthesis; biomass; catalysts; cellulose; chiral auxiliaries; D-allal; levoglucosenone; organocatalysts

Conference

International Conference on Green Chemistry (ICGC-4), IUPAC International Conference on Green Chemistry, ICGC, Green Chemistry , 4th, Foz do Iguaçu, Brazil, 2012-08-25–2012-08-29

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About the article

Published Online: 2013-07-10

Published in Print: 2013-07-10


Citation Information: Pure and Applied Chemistry, Volume 85, Issue 8, Pages 1683–1692, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/PAC-CON-12-11-10.

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