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Volume 88, Issue 10-11

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Cyclotriphosphazene, an old compound applied to the synthesis of smart dendrimers with tailored properties

Anne-Marie Caminade / Armelle Ouali
  • CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France
  • Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France
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/ Aurélien Hameau
  • CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France
  • Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France
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/ Régis Laurent
  • CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France
  • Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France
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/ Cyrille Rebout
  • CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France
  • Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France
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/ Béatrice Delavaux-Nicot
  • CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France
  • Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France
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/ Cédric-Olivier Turrin
  • CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France
  • Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France
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/ Kathleen Moineau Chane-Ching
  • CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France
  • Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France
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/ Jean-Pierre Majoral
  • CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France
  • Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2016-10-20 | DOI: https://doi.org/10.1515/pac-2016-0711

Abstract

The versatile reactivity of hexachlorocyclotriphosphazene (N3P3Cl6) has been developed for the synthesis of specifically engineered dendrimers. Dendrimers are hyperbranched macromolecules built by concentric layers constituted of associated monomeric units. Many of the properties of dendrimers depend on the type of their surface (terminal) functions, which are generally all identical. For some specific purposes, it is desirable to have one function that is different at the level of the core. Hexachlorocyclotriphosphazene offers the possibility to differentiate the reactivity of one (or more) Cl from the others, for producing specifically engineered dendritic tools. These specific reactions on N3P3Cl6 have produced highly dense dendrimers, Janus dendrimers (two faces), tools for functionalizing materials, with uses as catalysts, as chemical sensors, for trapping CO2, for the culture of cells, or for imaging biological events. These properties will be emphasized in this review.

Keywords: chemical synthesis; dendrimers; ICPC-21; phosphorus chemistry

Dedicated to: the memory of the late Dr. Michel Keller, former PhD student in our group, accidentally deceased on May 18th 2016.

Article note:

A collection of invited papers based on presentations at the 21st International Conference on Phosphorous Chemistry (ICPC-21) held in Kazan, Russia, 5–10 June 2016.

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About the article

Published Online: 2016-10-20

Published in Print: 2016-11-01


Citation Information: Pure and Applied Chemistry, Volume 88, Issue 10-11, Pages 919–929, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1515/pac-2016-0711.

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