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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen


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1365-3075
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Volume 89, Issue 1

Issues

Synthesis and characterization of vinyl derivatives of naphthalene-2,7-diol as a photoluminescent dopant useful in optical materials

Małgorzata Gil
  • Corresponding author
  • Laboratory of Optical Fibers Technology, Faculty of Chemistry, Maria Curie-Skłodowska University, pl. M. Curie-Skłodowskiej 5, 20-031 Lublin, Poland
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  • De Gruyter OnlineGoogle Scholar
/ Beata Podkościelna
  • Department of Polymer Chemistry, Faculty of Chemistry, Maria Curie-Skłodowska University, pl. M. Curie-Skłodowskiej 5, 20-031 Lublin, Poland
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Barbara Gawdzik
  • Department of Polymer Chemistry, Faculty of Chemistry, Maria Curie-Skłodowska University, pl. M. Curie-Skłodowskiej 5, 20-031 Lublin, Poland
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  • De Gruyter OnlineGoogle Scholar
/ Andrzej Bartnicki
  • Department of Polymer Chemistry, Faculty of Chemistry, Maria Curie-Skłodowska University, pl. M. Curie-Skłodowskiej 5, 20-031 Lublin, Poland
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Wiesław Podkościelny
  • Laboratory of Optical Fibers Technology, Faculty of Chemistry, Maria Curie-Skłodowska University, pl. M. Curie-Skłodowskiej 5, 20-031 Lublin, Poland
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  • De Gruyter OnlineGoogle Scholar
/ Gokhan Demirci
  • Department of Polymer Chemistry, Faculty of Chemistry, Maria Curie-Skłodowska University, pl. M. Curie-Skłodowskiej 5, 20-031 Lublin, Poland
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  • De Gruyter OnlineGoogle Scholar
Published Online: 2016-12-23 | DOI: https://doi.org/10.1515/pac-2016-1002

Abstract

In this study synthesis and characterization of the new methacrylic derivatives of naphthalene-2,7-diol are presented. This reaction was performed in the three stages. In first stage 2,7-NAF was reacted with dimethyl sulfate in the NaOH solutions at 0°C. Next, the obtained 2,7-NAF.Me was modified by epichlorohydrine leading to epoxide compound (2,7-NAF.Me.EP). Finally, the reaction of opening oxirane rings by methacrylic acid was carried out. The chemical structures of all derivatives were confirmed by 1H and 13C NMR. Next, copolymerization reaction with methyl methacrylate (MMA), styrene (St) or divinylbenzene (DVB) was carried out. New monomer (2,7-NAF.MePM) possesses only one double bond and it can be used as a dopant in optical materials technology. The studies of their thermal properties were investigated by means TG/DTG/QMS coupled method. The influence of photoluminescence dopant on thermal stability of the obtained copolymers was also discussed.

Keywords: copolymerization; naphthalene-2,7-diol; NMR; photoluminescence; POC-16; thermogravimetric analysis

Article note:

A collection of invited papers based on presentations at the 16th International Conference on Polymers and Organic Chemistry (POC-16), Hersonissos (near Heraklion), Crete, Greece, 13–16 June 2016.

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About the article

Published Online: 2016-12-23

Published in Print: 2017-01-01


Citation Information: Pure and Applied Chemistry, Volume 89, Issue 1, Pages 111–123, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1515/pac-2016-1002.

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©2016 IUPAC & De Gruyter. This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License. For more information, please visit: http://creativecommons.org/licenses/by-nc-nd/4.0/.Get Permission

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