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Volume 89, Issue 3 (Mar 2017)

Issues

Hydroxylated phosphines as ligands for chalcogenide clusters: self assembly, transformations and stabilization

Maxim N. Sokolov
  • Corresponding author
  • Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Prospekt Lavrentyeva 3, 630090 Novosibirsk, Russia
  • Novosibirsk State University, ul. Pirogova 2, 630090 Novosibirsk, Russia
  • Kazan Federal University, 18 ul. Kremlyovskaya 420008, Kazan, Russia
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Alexander V. Anyushin
  • Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Prospekt Lavrentyeva 3, 630090 Novosibirsk, Russia
  • Novosibirsk State University, ul. Pirogova 2, 630090 Novosibirsk, Russia
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Rita Hernandez-Molina
  • Departamento de Química, Unidad Departamental de Química Inorgánica, Universidad de La Laguna, La Laguna, Tenerife, Spain
  • Instituto Universitario de Bioorganica Antonio Gonzalez, Avda Astrofis Fco, Sanchez 2, San Cristobal la Laguna 38206, Spain
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Rosa Llusar
  • Departamento de Química Física i Analítica, Universitat Jaume I, Av. Sos Baynat s/n, 12071 Castelló, Spain
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Manuel G. Basallote
  • Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, Facultad de Ciencias, and Instituto de Biomoléculas, INBIO, Universidad de Cádiz, Avda. República Saharahui s/n, Puerto Real, 11510 Cádiz, Spain
  • Other articles by this author:
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Published Online: 2017-03-17 | DOI: https://doi.org/10.1515/pac-2017-0105

Abstract

This contribution is a documentation of recent advances in the chemistry of chalcogenide polynuclear transition metal complexes coordinated with mono- and di-phosphines functionalized with hydroxo groups. A survey of complexes containing tris(hydroxymethyl)phosphine (THP) is presented. The influence of the alkyl chain in bidentate phosphines, bearing the P–(CH2)x–OH arms, is also analyzed. Finally, isolation and structure elucidation of the complexes with HP(OH)2, P(OH)3, As(OH)3, PhP(OH)2, stabilized by coordination to Ni(0) and Pd(0) centers embedded into chalcogenide clusters, is discussed.

Keyword:: ICPC-21

Article note:

A collection of invited papers based on presentations at the 21st International Conference on Phosphorous Chemistry (ICPC-21) held in Kazan, Russia, 5–10 June 2016.

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About the article

Published Online: 2017-03-17

Published in Print: 2017-03-01


Citation Information: Pure and Applied Chemistry, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1515/pac-2017-0105.

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