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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen

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IMPACT FACTOR 2017: 5.294

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1365-3075
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Volume 90, Issue 3

Issues

Producing superhydrophobic/oleophobic coatings on Cultural Heritage building materials

Maria J. Mosquera
  • Corresponding author
  • Nanomaterials Group TEP-243, Departamento de Química-Física, Facultad de Ciencias, Universidad de Cádiz, Campus Río San Pedro, Puerto Real (Cádiz) 11510, Spain
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Luis A.M. Carrascosa
  • Nanomaterials Group TEP-243, Departamento de Química-Física, Facultad de Ciencias, Universidad de Cádiz, Campus Río San Pedro, Puerto Real (Cádiz) 11510, Spain
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Nabil Badreldin
  • Nanomaterials Group TEP-243, Departamento de Química-Física, Facultad de Ciencias, Universidad de Cádiz, Campus Río San Pedro, Puerto Real (Cádiz) 11510, Spain
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2017-11-22 | DOI: https://doi.org/10.1515/pac-2017-0404

Abstract

Water is the main vehicle of decay agents in Cultural Heritage building materials exposed to weathering. In this work, a simple method to produce superhydrophobic/oleophobic coatings building materials, including under outdoors conditions, has been developed. In addition, a study of the behavior of the developed coatings on different substrates (limestone, granite, concrete and wood) is reported. The addition of 40 nm-SiO2 nanoparticles to a fluoroalkylsilane reduces surface energy and produces a Cassie-Baxter surface in all the materials evaluated. It promotes high static contact angle values of around 160°, and a contact angle hysteresis of around 3°, giving rise to repellence. The building surfaces also demonstrate an excellent self-cleaning performance. The coatings maintain the building materials esthetics as required in the Cultural Heritage field. Finally, the coating presents a long-lasting performance due to condensation reactions producing effective grafting to the four building materials evaluated.

This article offers supplementary material which is provided at the end of the article.

Keywords: 40-nm silica particles; building material; ChemCultHerit; Cultural Heritage; fluoroalkylsilane; long-lasting properties; oleophobicity; self-cleaning; superhydrophobicity

Article note:

A special issue containing invited papers on Chemistry and Cultural Heritage (M.J. Melo, A. Nevin and P. Baglioni, editors.

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About the article

Published Online: 2017-11-22

Published in Print: 2018-02-23


Citation Information: Pure and Applied Chemistry, Volume 90, Issue 3, Pages 551–561, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1515/pac-2017-0404.

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