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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen


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1365-3075
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Volume 91, Issue 10

Issues

Stability of PMMA-grafted/Ti hybrid biomaterial interface in corrosive media

Tiphaine Schott / Françoise Liautaud / Sebastien Kriegel
  • Université de Strasbourg, CNRS UMR 7504, Institut de Physique et Chimie des Matériaux de Strasbourg (IPCMS), 23 rue du Loess BP 43, 67034 Strasbourg, France
  • Other articles by this author:
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/ Jacques Faerber
  • Université de Strasbourg, CNRS UMR 7504, Institut de Physique et Chimie des Matériaux de Strasbourg (IPCMS), 23 rue du Loess BP 43, 67034 Strasbourg, France
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  • De Gruyter OnlineGoogle Scholar
/ Wenjia He
  • Université de Strasbourg, CNRS UMR 7504, Institut de Physique et Chimie des Matériaux de Strasbourg (IPCMS), 23 rue du Loess BP 43, 67034 Strasbourg, France
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/ Patrick Masson
  • Université de Strasbourg, CNRS UMR 7504, Institut de Physique et Chimie des Matériaux de Strasbourg (IPCMS), 23 rue du Loess BP 43, 67034 Strasbourg, France
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/ Geneviève Pourroy
  • Corresponding author
  • Université de Strasbourg, CNRS UMR 7504, Institut de Physique et Chimie des Matériaux de Strasbourg (IPCMS), 23 rue du Loess BP 43, 67034 Strasbourg, France
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/ Adele CarradòORCID iD: https://orcid.org/0000-0003-1094-4075
Published Online: 2019-06-22 | DOI: https://doi.org/10.1515/pac-2018-1218

Abstract

The stability of interfaces between polymethyl methacrylate (PMMA) and titanium (Ti) are tested in a Ringer solution that is an aggressive medium usually used for biomaterial evaluation. The devices are PMMA-grafted/Ti elaborated via a “grafting-from” method involving three steps, the alkali activation of Ti sheets, their functionalization with an initiator of polymerization through a phosphonate anchoring group and the growth of PMMA brushes. Electrochemical characterizations demonstrate that the stability of the PMMA-grafted/Ti interface in biological medium is satisfactory and that the grafting of PMMA is even acting as a protective barrier for titanium. Indeed, PMMA-grafted/Ti remains passive in Ringer solution until at least +3 V/SCE (saturated calomel electrode), even under inflammatory conditions, while localized corrosion was measured on as-received titanium in similar conditions. This protecting role is attributed to the grafted interface, since spin-coated PMMA does not decrease the corrosion sensitivity of titanium.

Keywords: biocompatibility; corrosion; Eurasia 2018; grafting from; inflammatory conditions; interface; PMMA; protective film; sandwich; titanium

Article note

A collection of invited papers based on presentations at the 15th Eurasia Conference on Chemical Sciences (EuAsC2S-15) held at Sapienza University of Rome, Italy, 5–8 September 2018.

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About the article

Published Online: 2019-06-22

Published in Print: 2019-10-25


Citation Information: Pure and Applied Chemistry, Volume 91, Issue 10, Pages 1617–1629, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1515/pac-2018-1218.

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