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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen


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Volume 91, Issue 6

Issues

Double perovskites REBaCo2−xMxO6−δ (RE=La, Pr, Nd, Eu, Gd, Y; M=Fe, Mn) as energy-related materials: an overview

Dmitry S. Tsvetkov
  • Department of Physical and Inorganic Chemistry, Institute of Natural Sciences and Mathematics, Ural Federal University, Ekaterinburg 620000, Russia
  • Other articles by this author:
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/ Ivan L. Ivanov
  • Department of Physical and Inorganic Chemistry, Institute of Natural Sciences and Mathematics, Ural Federal University, Ekaterinburg 620000, Russia
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Dmitry A. Malyshkin
  • Department of Physical and Inorganic Chemistry, Institute of Natural Sciences and Mathematics, Ural Federal University, Ekaterinburg 620000, Russia
  • Institute of High-Temperature Electrochemistry UB RAS, Ekaterinburg 620137, Russia
  • Other articles by this author:
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/ Anton L. Sednev
  • Department of Physical and Inorganic Chemistry, Institute of Natural Sciences and Mathematics, Ural Federal University, Ekaterinburg 620000, Russia
  • Institute of High-Temperature Electrochemistry UB RAS, Ekaterinburg 620137, Russia
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Vladimir V. Sereda
  • Department of Physical and Inorganic Chemistry, Institute of Natural Sciences and Mathematics, Ural Federal University, Ekaterinburg 620000, Russia
  • Institute of High-Temperature Electrochemistry UB RAS, Ekaterinburg 620137, Russia
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Andrey Yu. Zuev
  • Corresponding author
  • Department of Physical and Inorganic Chemistry, Institute of Natural Sciences and Mathematics, Ural Federal University, Ekaterinburg 620000, Russia
  • Email
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Published Online: 2019-05-18 | DOI: https://doi.org/10.1515/pac-2018-1103

Abstract

This work, based on the experimental and theoretical research carried out by the authors during the last decade, presents an overview of formation, stability and defect thermodynamics, crystal structure, oxygen nonstoichiometry, chemical strain and transport properties of the double perovskites REBaCo2−xMxO6−δ (RE = La, Pr, Nd, Eu, Gd, Y; M = Fe, Mn). These mixed-conducting oxides are widely regarded as promising materials for various energy conversion and storage devices. Attention is focused on (i) thermodynamics of formation and disordering, oxygen nonstoichiometry, crystal and defect structure of the double perovskites REBaCo2−xMxO6−δ, as well as their thermodynamic stability and the homogeneity ranges of solid solutions, (ii) their overall conductivity and Seebeck coefficient as functions of temperature and oxygen partial pressure and (iii) the anisotropic chemical strain of their crystal lattice. The relationships between the peculiarities of the defect structure and related properties of the double perovskites are analysed.

Keywords: defect structure; defect thermodynamics; double perovskites; electrode; HTMC-XVI; membrane; mixed conductor

Article note

A collection of invited papers based on presentations at the 16th International IUPAC Conference on High Temperature Chemistry (HTMC-XVI), held in Ekaterinburg, Russia, 2–6 July 2018.

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About the article

Published Online: 2019-05-18

Published in Print: 2019-06-26


Funding Source: Russian Foundation for Basic Research

Award identifier / Grant number: 18-33-20243\18

This work was supported by Russian Foundation for Basic Research, Funder Id: http://dx.doi.org/10.13039/501100002261 (Grant No. 18-33-20243\18).


Citation Information: Pure and Applied Chemistry, Volume 91, Issue 6, Pages 923–940, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1515/pac-2018-1103.

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