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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen


IMPACT FACTOR 2017: 5.294

CiteScore 2017: 3.42

SCImago Journal Rank (SJR) 2017: 1.212
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1365-3075
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Volume 89, Issue 1

Issues

New approach in the application of lignin for the synthesis of hybrid materials

Beata Podkościelna
  • Corresponding author
  • Department of Polymer Chemistry, Faculty of Chemistry, Maria Curie-Skłodowska University, pl. M. Curie-Skłodowskiej 5, 20-031 Lublin, Poland
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  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Marta Goliszek
  • Department of Polymer Chemistry, Faculty of Chemistry, Maria Curie-Skłodowska University, pl. M. Curie-Skłodowskiej 5, 20-031 Lublin, Poland
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Olena Sevastyanova
  • KTH, Royal Institute of Technology, Department of Fibre and Polymer Technology, Division of Wood Chemistry and Pulp Technology, SE-10044 Stockholm, Sweden
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2016-11-26 | DOI: https://doi.org/10.1515/pac-2016-1009

Abstract

In this study, a novel method for the synthesis of hybrid, porous microspheres, including divinylbenzene (DVB), triethoxyvinylsilane (TEVS) and methacrylated lignin (L-Met), is presented. The methacrylic derivatives of kraft lignin were obtained by reaction with methacryloyl chloride according to a new experimental protocol. The course of the modification of lignin was confirmed by attenuated total reflectance (ATR-FTIR) and nuclear magnetic resonance (NMR) spectroscopy. The emulsion-suspension polymerization method was employed to obtain copolymers of DVD, TEVS and L-Met in spherical forms. The porous structures and morphologies of the obtained lignin-containing functionalized microspheres were investigated by low-temperature nitrogen adsorption data and scanning electron microscopy (SEM). The microspheres are demonstrated to be mesoporous materials with specific surface areas in the range of 430–520 m2/g. The effects of the lignin component on the porous structure, shape, swelling and thermal properties of the microspheres were evaluated.

Keywords: biomaterials; lignin; microspheres; NMR; POC-16; Polymerization; surface properties; synthesis; thermal properties

Article note:

A collection of invited papers based on presentations at the 16th International Conference on Polymers and Organic Chemistry (POC-16), Hersonissos (near Heraklion), Crete, Greece, 13–16 June 2016.

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About the article

Published Online: 2016-11-26

Published in Print: 2017-01-01


Citation Information: Pure and Applied Chemistry, Volume 89, Issue 1, Pages 161–171, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1515/pac-2016-1009.

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