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Polish Journal of Chemical Technology

The Journal of West Pomeranian University of Technology, Szczecin

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Volume 14, Issue 2 (Jan 2012)


Synthesis, characterization and analytical applications of chelating resin containing orcinol

Bhavna Shah
  • Department of Chemistry, Veer Narmad South Gujarat University, Swat, Gujarat, India
/ Ajay Shah
  • Department of Chemistry, Polytechnic, Vidhyabharti Trust, Umrakh, Bardoli, Gujarat, India
/ Nayan Patel
  • Department of Chemistry, Veer Narmad South Gujarat University, Swat, Gujarat, India
/ Pathik Shah
  • Central Institute of Plastics Engineering & Technology, Vatva, Ahmedabad. Gujarat. India
Published Online: 2012-07-02 | DOI: https://doi.org/10.2478/v10026-012-0076-3

Synthesis, characterization and analytical applications of chelating resin containing orcinol

A chelating resin based on Salicylic acid-Formaldehyde copolymer, containing Orcinol (SFO), has been synthesized and characterized on the basis of Elemental Analysis, Particle Size Distribution, FT-IR Analysis, XRD, SEM and Optical Photographs. The Physico-Chemical properties have been studied. This resin is highly stable in acidic and alkaline solutions and has been studied as a chelating sorbent for heavy metal ions and transition metal ions. The Exchange capacity order is Ni(II) > Cu(II) > Zn(II) > Cd(II) > Pb(II). The effect of nature and concentration of different electrolytes on distribution coefficient (Kd) for metal ions have been investigated. Separation of synthetic mixtures containing Cu(II)-Pb(II), Ni(II)-Cd(II) and Brass constituents has been carried out using a column prepared from the synthesized chelating resin. The developed procedure was also tested for the removal of Cd(II) and Pb(II) from natural water of Purna River near by Navsari, Gujarat, India.

Keywords: Analytical Separation; Chelating Resin; Column Operation; Copolymer; Exchange Capacity

  • Rao, G. P. C., Rao, M. M., & Veni, S. S. (2006). Pre-concentration of total chromium on Dowex 50WX8 resin loaded with 2-amino-benzenethiol. International Journal of Environmental Analytical Chemistry. 86 (14), 1095-1103. DOI:10.1080/03067310600847369.

  • Cheng, C., Jin, N. W., Li, X, & Ai M. L. (2012). Preparation of new hyper cross-linked chelating resin for adsorption of Cu2+ and Ni2+ from water. Chinese Chemical Letters. 23(2), 245-248. DOI:10.1016/j.cclet.2011.10.019. [Web of Science] [Crossref]

  • Chandra, D., Kumar, D. S., & Bhaumik, A. (2010). A fluorophore grafted 2D-hexagonal mesoporous organosilica: excellent ion exchanger for the removal of heavy metal ions from wastewater. Microporous Mesoporous Material. 128, 34-40. DOI:10.1016/j.micromeso.2009.07.024.

  • Park, I. H., & Kim, K. M. (2005). Preparation of chelating resins containing a pair of neighboring carboxylic acid groups and the adsorption characteristics for heavy metal ions. Separation Science and Technology. 40, 2963-2986. DOI:10.1080/01496390500338060. [Crossref]

  • Gurnule, W. B., & Patel, D. B. (2011). Metal ion binding properties of a copolymer resin: synthesis, characterization, and its applications. Polymer bulletin. 66, 803-820. DOI 10.1007/S00289-010-0385-8. [Crossref] [Web of Science]

  • Singh, D.K, & Srivastava, M. (2006). Synthesis Characteristic and Analytical Applications of New chelating resin containing p-Bromophenylhydromaxic acid. Journal of Liquid Chromatography & Related Technologies. 29(10), 1433-1440. DOI: 10.1080/10826070600674828. [Crossref]

  • Mohan, S., & Sreelakshmi, G. (2008). Fixed bed column study for heavy metal removal using phosphate treated rice husk. Journal of Hazardous Material. 153, 75-82. DOI: 10.1016/j.jhazmat.2007.08.021. [Crossref]

  • Dogan, C. E. & Akcin, G. (2007). Solid phase extraction and determination of lead in water sample using silica gel homogeneously modified by thiosalicylic add. Analytical Letter. 40(13), 2524-2543. DOI: 10.1080/00032710701585016. [Crossref] [Web of Science]

  • Helfferich, R. (1962). Ion Exchange Resin. McGraw Hills, New York.

  • Kunin, R. (1958). Ion Exchange Resin. (2nd edition) Wiley London.

  • Vogel, S. (2009). Textbook of Qualitative Chemical Analysis. 6th edition Cambridge University Press, Cambridge.

  • Shah, B. A., Shah, A. V., & Shah, P. M. (2008). Metal ions uptake by chelating resin derived from o-substituted benzoic acid and its synthesis, characterization and properties. Macro-molecular Symposia. 274, 81-90. DOI: 10.1002/masy.200851412. [Crossref]

  • Sun, C., Qu, R., Ji, C., Wang, Q., Sun, Y., & Cheng, G. (2006). A chelating resin containing S, N and O atoms: Synthesis and adsorption properties for Hg(II). European Polymer Journal. 42(1), 188-194. DOI: 10.1016/j.eurpolymj.2005.06.024. [Crossref]

  • Samal, S., Acharya, S., Dey, R.K, & Ray, A. R. (2003). Synthesis, characterization and metal ion uptake studies of chelating resin derived from formaldehyde / furfuraldehyde condensed phenolic schiff base of 4, 4'-diaminophenylmethane and o-hydroxyacetophenone. Journal of Applied Polymer Science.88 (2), 570-581. DOI: 10.1002/app.11715. [Crossref]

  • Shah, B. A., Shah, A. V., & Patel, N. B. (2008). A benign approach of microwave assisted synthesis of copolymer with improved thermal, spectral and ion exchange properties. Iranian Polymer Journal. 17 (1), 3-17. http://journal.ippi.ac.ir/journals.php?tab=-1&v=17&n=1. http://journal.ippi.ac.ir/journals.php?tab=-1&v=17&n=1

  • Shah, B. A., Shah, A. V., & Shah, P. M. (2010). Selective sorption of heavy metal ions from aqueous solutions using m-cresol based chelating resin and its analytical applications. Iranian Journal of Chemistry and Chemical Engineering 29(2), 49-58. http://www.sid.ir/en/VEWSSID/J_pdf/84320105407.pdf. http://www.sid.ir/en/VEWSSID/J_pdf/84320105407.pdf

  • Bhatt, R. R., & Shah, B. A. (2007). Studies of Chelation Ion-exchange Properties of Copolymer Resin Derived from Salicylic Acid and its Analytical Applications Iranian polymer journal. 16 (3), 173-184. http://journal.ippi.ac.ir/journals.php7ta-b=-1&v=16&n=3. http://journal.ippi.ac.ir/journals.php7ta-b=-1&v=16&n=3

  • Rivas, B. R., Peric, I. M., & Villegas, S. (2010). Synthesis and metal ion uptake properties of water-insoluble functional copolymers: removal of metal ions with environmental impact. Polymer Bulletin. 65 (9), 917-928. DOI: 10.1007/s00289-010-0304-z. [Crossref] [Web of Science]

  • Demirbas, A., Pehivan, E., Gode, F., Altun, T., & Arslan, G. (2005). Adsorption of Cu(II), Zn(II), Ni(II), Pb(II) and Cd(II) from aqueous solution on Amberlite IR-120 synthetic resin. Journal of Colloid and Interface Science. 282:20-25. DOI: 10.1016/j.jcis.2004.08.147. [Web of Science] [Crossref]

  • Bajpal, A. K., & Rai, L. (2010). Removal of chromium ion from aqueous solution by biosorption on to ternary bio-polymer microspheres. Indian Journal of Chemical Technology. 17:17-27. http://nopr.niscair.res.in/bitstream/123456789/7271/1/IJCT%2017%281%29%2017-27.pdf. http://nopr.niscair.res.in/bitstream/123456789/7271/1/IJCT%2017%281%29%2017-27.pdf

About the article

Published Online: 2012-07-02

Published in Print: 2012-01-01

Citation Information: Polish Journal of Chemical Technology, ISSN (Online) 1899-4741, ISSN (Print) 1509-8117, DOI: https://doi.org/10.2478/v10026-012-0076-3. Export Citation

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