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Polish Journal of Chemical Technology

The Journal of West Pomeranian University of Technology, Szczecin

4 Issues per year


IMPACT FACTOR 2016: 0.725
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ISSN
1899-4741
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Volume 14, Issue 3 (Oct 2012)

Issues

Simulation and sensitivity analysis for biodiesel production in a reactive distillation column

Madhu Agarwal / Kailash Singh / S.P. Chaurasia
Published Online: 2012-10-31 | DOI: https://doi.org/10.2478/v10026-012-0085-2

The conventional process for biodiesel production by transesterification is still expensive due to a need of high excess of alcohol required and its recovery by distillation. The use of a reactive distillation process can reduce the amount of alcohol in the feed stream as it works on a simultaneous reaction and separation. In the present study, a mathematical model has been developed for biodiesel production from triglycerides in a reactive distillation column, which has been validated with the reported data and CHEMCAD results. The effects of process parameters such as methanol to oil feed ratio, feed temperature, and reaction time have been investigated. The sensitivity analysis shows that yield of ester increases with methanol to oil ratio and number of stages, however, it decreases with fl ow rate. The MATLAB simulated results show that methanol to oil molar ratio of 5:1 produces 90% (by wt.) of methyl ester in a residence time of 4.7 minutes.

Keywords: Biodiesel; reactive distillation; modeling; simulation; transesterification; sensitivity analysis.

  • 1. Fangrui, M. & Milford, A.H. (1999). Biodiesel production: a review. Bioresource Technology. 70 (1), 1-15. doi:10.1016/ S0960-8524(99)00025-5.CrossrefGoogle Scholar

  • 2. Kiss, A.A., Dimian, A.C. & Rothenberg, G. (2008). Biodiesel by catalytic reactive distillation powered by metal oxides. Energy Fuels. 22 (1), 598-604.Web of ScienceCrossrefGoogle Scholar

  • 3. Giessler, S., Danilov, R.Y., Pisarenko, R.Y., Serafi mov, L.A., Hasebe, S. & Hashimoto, I. (2001). Systematic structure generation for reactive distillation processes. Computers& Chemical Engineering. 25 (1), 49-60. doi:10.1016/S0098- 1354(00)00632-3.CrossrefGoogle Scholar

  • 4. He, B.B., Singh, A.P. & Thompson, J.C. (2006). A novel continuous-fl ow reactor using reactive distillation for biodiesel production. Transactions of the ASABE. 49 (1), 107-112.Google Scholar

  • 5. Pai, R.A., Doherty, M.F. & Malone, M.F. (2002). Design of reactive extraction systems for bioproduct recovery. AIChEJournal. 48 (3), 514-526. DOI: 10.1002/aic.690480310.CrossrefGoogle Scholar

  • 6. Chin, S.Y., Mohamed, A.R., Ahmad, A.L. & Bhatia, S. (2006). Esterifi cation of palmitic acid with iso-propanol in a catalytic distillation column: Modeling and simulation studies. International Journal of Chemical Reactor Engineering. 4 (4), 32.Google Scholar

  • 7. Kiss, A.A., Omota, F., Dimian, A.C. & Rothenberg, G. (2006). The heterogeneous advantage: biodiesel by catalytic reactive distillation. Topics in Catalysis. 40 (1), 141-150. DOI: 10.1007/s11244-006-0116-4.CrossrefGoogle Scholar

  • 8. Omota, F., Dimian, A.C. & Bliek, A. (2003). Fatty acid esterifi cation by reactive distillation. Chemical EngineeringScience. 58, 3159-3174. doi:10.1016/S0009-2509(03)00165-9.CrossrefGoogle Scholar

  • 9. He, B.B., Singh, A.P. & Thompson, J.C. (2005). Experimental optimization of a continuous-fl ow reactive distillation reactor for biodiesel production. Transactions of the ASAE. 48 (6), 2237-2243.Google Scholar

  • 10. Bhatia, S., Ahmad, A.L., Mohamed, A.R. & Chin, S.Y. (2006). Production of isopropyl palmitate in a catalytic distillation column: Experimental studies. Chemical EngineeringScience. 61 (22), 7436-7447. doi:10.1016/j.ces.2006.08.039.CrossrefGoogle Scholar

  • 11. Singh, A.P., Thompson, J.C. & He, B.B. In A continuous--fl ow reactive distillation reactor for biodiesel preparation fromseed oils, ASAE/CSAE Annual International Meeting, Ottawa, Ontario, Canada, 1-4 August, 2004; Ottawa, Ontario, Canada, 2004. Paper number 046071.Google Scholar

  • 12. Taylor, R. & Krishna, R. (2000). Modelling reactive distillation. Chemical Engineering Science. 55 (22), 5183-5229. doi:10.1016/S0009-2509(00)00120-2.CrossrefGoogle Scholar

  • 13. Mattalana, L.G., Gutierrez, L.F. & Cardona C.A. In Biodiesel Production by reactive distillation, R Distillation - enpromer2005.eq.ufrj.br., 2005; 2005; pp 1-9.Google Scholar

  • 14. Thotla, S. & Mahajani, S. (2009). Reactive distillation with side draw. Chemical Engineering and Processing: ProcessIntensifi cation. 48 (4), 927-937. DOI: 10.1016/j.cep.2008.12.007.CrossrefGoogle Scholar

  • 15. Steinigeweg, S. & Gmehling, J. (2003). Esterifi cation of a fatty acid by reactive distillation. Ind. Eng. Chem. Res. 42 (15), 3612-3619.CrossrefGoogle Scholar

  • 16. He, B. (2006.). A novel continuous-fl ow reactor using reactive distillation for biodiesel production. A report, National Institute of Advanced Transport Technology, University of Idaho.Google Scholar

  • 17. Santandera, C.M.G., Sandra Marcela Gómez Rueda, Nívea De, Lima da Silvaa, Aline Carvalho da Costa, Rubens Maciel Filhoa, Regina, M. & Maciela., W. (2010). Simulation of the reactive distillation process for biodiesel production. 20th European Symposium on Computer Aided Process Engineering- ESCAPE20.Google Scholar

  • 18. Bambase, M.E., Nakamura, N., Tanaka, J. & Matsumura, M. (2007). Kinetics of hydroxide-catalyzed methanolysis of crude sunfl ower oil for the production of fuel-grade methyl esters. Journal of Chemical Technology & Biotechnology. 82 (3), 273-280. DOI: 10.1002/jctb.1666.CrossrefGoogle Scholar

  • 19. Gupta, S.K., Numerical methods for engineers. New Age International: New Delhi, 2006; p 422.Google Scholar

  • 20. Noureddini, H. & Zhu, D. (1997). Kinetics of transesterifi cation of soybean oil. Journal of the American Oil Chemists’Society. 74 (11), 1457-1463. DOI: 10.1007/s11746-997-0254-2.CrossrefGoogle Scholar

  • 21. Freedman, B., Butterfi eld, R.O. & Pyrde, E. (1986). Transesterifi cationkinetics of soybean oil. J. Am. Oil Chem.Soc. 63, 1375-1380. DOI: 10.1007/BF02679606.CrossrefGoogle Scholar

  • 22. Darnoko, D. & Cheryan, M. (2000). Kinetics of palm oil transesterifi cation in a batch reactor. Journal of the AmericanOil Chemists’ Society. 77 (12), 1263-1267. DOI: 10.1007/ s11746-000-0198-y.CrossrefGoogle Scholar

  • 23. Simasatitkul, L., Siricharnsakunchai, P., Patcharavorachot, Y., Assabumrungrat, S. & Arpornwichanop, A. (2011). Reactive distillation for biodiesel production from soybean oil. Korean Journal of Chemical Engineering. 28 (3), 649-655. DOI: 10.1007/s11814-010-0440-z. CrossrefGoogle Scholar

About the article

Received:

Accepted:

Published Online: 2012-10-31

Published in Print: 2012-10-01


Citation Information: Polish Journal of Chemical Technology, ISSN (Online) 1899-4741, ISSN (Print) 1509-8117, DOI: https://doi.org/10.2478/v10026-012-0085-2.

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