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Journal of Polymer Engineering

Editor-in-Chief: Grizzuti, Nino


IMPACT FACTOR 2018: 1.072

CiteScore 2018: 1.17

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Source Normalized Impact per Paper (SNIP) 2018: 0.691

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2191-0340
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Volume 34, Issue 7

Issues

Synthesis of a novel class of mixed-type surfmers and their properties in water

Linyu Li
  • School of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu, Sichuan 610500, China
  • Other articles by this author:
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/ Ming Duan
  • School of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu, Sichuan 610500, China
  • State Key Laboratory of Oil/Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, Sichuan 610500, China
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/ Shenwen Fang
  • Corresponding author
  • School of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu, Sichuan 610500, China
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/ Liehui Zhang
  • State Key Laboratory of Oil/Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, Sichuan 610500, China
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/ Weihong Long
  • School of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu, Sichuan 610500, China
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/ Hu Wang
  • State Key Laboratory of Oil/Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, Sichuan 610500, China
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Published Online: 2014-05-27 | DOI: https://doi.org/10.1515/polyeng-2013-0111

Abstract

Three new mixed-type surfmers were synthesized using poly(propylene oxide)/poly(ethylene oxide)/poly(propylene oxide) (PPO-PEO-PPO) having terminal tertiary amine group as the basic material: (1) PPO-PEO-PPO with a carboxyl group on one end (MTA); (2) PPO-PEO-PPO with a quaternary ammonium group on one end (JTA); (3) PPO-PEO-PPO with a quaternary ammonium group on one end and a carboxyl group on the other end (MJTA). These products were confirmed by 1H-NMR and FT-IR. Similar to PPO-PEO-PPO, the three surfmers have a cloud point (Tcp). Both MJTA and MTA have lower Tcp than JTA. However, the cloud points of both MJTA-Na+ and MTA-Na+ are much higher than JTA. Their different Tcp may be caused by their strength of dissociation in water. In addition, at a high temperature (T>Tcp of MJTA), MJTA-Na+ can be considered a pH-sensitive surfactant. At neutral and alkaline conditions, it can be used as an emulsifier. However, at acidic conditions, it loses its emulsification property. MTA-Na+ has the same property.

Keywords: pH-sensitive; poly(ethylene oxide); surfmer

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About the article

Corresponding author: Shenwen Fang, School of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu, Sichuan 610500, China, e-mail:

aPresent address: 8 Xindu Avenue, Xindu District, Chengdu, Sichuan 610500, PR China


Received: 2013-05-03

Accepted: 2014-05-07

Published Online: 2014-05-27

Published in Print: 2014-09-01


Citation Information: Journal of Polymer Engineering, Volume 34, Issue 7, Pages 597–603, ISSN (Online) 2191-0340, ISSN (Print) 0334-6447, DOI: https://doi.org/10.1515/polyeng-2013-0111.

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