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Radiochimica Acta

International Journal for chemical aspects of nuclear science and technology

Ed. by Qaim, Syed M.

12 Issues per year


IMPACT FACTOR 2016: 1.271
5-year IMPACT FACTOR: 1.286

CiteScore 2016: 1.20

SCImago Journal Rank (SJR) 2016: 0.486
Source Normalized Impact per Paper (SNIP) 2016: 0.761

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2193-3405
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Volume 88, Issue 9-11 (Sep 2000)

Issues

Mixed Ca2+/UO22+/CO32- complex formation at different ionic strengths

S. N. Kalmykov / Gregory R. Choppin
Published Online: 2009-09-25 | DOI: https://doi.org/10.1524/ract.2000.88.9-11.603

Fluorescence spectroscopy was used to study the Ca2+/UO22+/CO32- solution system at different ionic strengths. Fluorescent titrations confirmed formation of Ca2UO2(CO3)3 complex for which the values of log β213 were measured at 0.1, 0.3, 0.7, 1.0 and 3.0 m (NaClO4) at pcH = 8.1. Specific Interaction Theory (SIT) was used to correlate the log β213 values as a function of ionic strength. The value obtained for log β0213 (I = 0) was 29.8 ± 0.7, indicating that Ca2UO2(CO3)3 was the predominant specie at the pH 8 in calcium rich, oxic waters.

About the article

Published Online: 2009-09-25

Published in Print: 2000-09-01


Citation Information: Radiochimica Acta, ISSN (Online) 2193-3405, ISSN (Print) 0033-8230, DOI: https://doi.org/10.1524/ract.2000.88.9-11.603.

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