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Radiochimica Acta

International Journal for chemical aspects of nuclear science and technology

Editor-in-Chief: Qaim, Syed M.

IMPACT FACTOR 2017: 1.202

CiteScore 2017: 1.22

SCImago Journal Rank (SJR) 2017: 0.409
Source Normalized Impact per Paper (SNIP) 2017: 0.869

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Volume 89, Issue 11-12


Physico-chemical characterization of seaborgium as oxide hydroxide

S. Hübener / S. Taut / A. Vahle / R. Dressler / B. Eichler / H. W. Gäggeler / D.T. Jost / D. Piguet / A. Türler / W. Brüchle
Published Online: 2009-09-25 | DOI: https://doi.org/10.1524/ract.2001.89.11-12.737

Seaborgium (Sg; element 106) was studied in comparison with tungsten in the O2-H2O(g)/SiO2(s)-system using high temperature on-line isothermal gas chromatography. The 21-s nuclide 266Sg was produced in the 248Cm+22Ne reaction at a beam energy of 119 MeV. The reaction products were continuously transported by a He(MoO3)-jet to the chromatography apparatus HITGAS. Group 6 element oxide hydroxide molecules volatile at temperatures above 1000 K were formed at 1325 K by adding humid oxygen as reactive gas. 266Sg was unambiguously detected after gas chromatographic separation by measuring 266Sg-262Rf mother-daughter α-sf correlations. The experimental results demonstrate the volatility of Sg in humid oxygen, presumably as Sg oxide hydroxide, a behavior typical for both U(VI) and the group 6 elements.

About the article

Published Online: 2009-09-25

Published in Print: 2001-11-01

Citation Information: Radiochimica Acta, Volume 89, Issue 11-12, Pages 737–742, ISSN (Online) 2193-3405, ISSN (Print) 0033-8230, DOI: https://doi.org/10.1524/ract.2001.89.11-12.737.

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