International Journal for chemical aspects of nuclear science and technology
Ed. by Qaim, Syed M.
12 Issues per year
IMPACT FACTOR 2016: 1.271
5-year IMPACT FACTOR: 1.286
CiteScore 2016: 1.20
SCImago Journal Rank (SJR) 2016: 0.486
Source Normalized Impact per Paper (SNIP) 2016: 0.761
X-ray absorption fine structure spectroscopy of plutonium complexes with bacillus sphaericus
Knowledge of the plutonium complexes formed with bacterial cells is critical for predicting the influence of microbial interactions on the migration behavior of actinides in the environment. This investigation describes the interaction of plutonium(VI) with cells of the aerobic soil bacteria, Bacillus sphaericus. The studies include the quantification of carboxylate and phosphate functional groups on the cell walls by potentiometric titration and the determination of the plutonium speciation by X-ray absorption fine structure (XAFS). Extended-XAFS (EXAFS) was used to determine the identity of the Pu(VI) interfacial complex with the bacteria, and the Pu(VI) was found primarily bound to phosphate groups on the cell surface. No carboxylate complexation was detected.
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