Jump to ContentJump to Main Navigation
Show Summary Details
More options …

Radiochimica Acta

International Journal for chemical aspects of nuclear science and technology

Ed. by Qaim, Syed M.

12 Issues per year


IMPACT FACTOR 2016: 1.271
5-year IMPACT FACTOR: 1.286

CiteScore 2016: 1.20

SCImago Journal Rank (SJR) 2016: 0.486
Source Normalized Impact per Paper (SNIP) 2016: 0.761

Online
ISSN
2193-3405
See all formats and pricing
More options …
Volume 92, Issue 3 (Mar 2004)

Issues

An EXAFS and TRLFS study of the sorption of trivalent actinides onto smectite and kaolinite

Thorsten Stumpf / C. Hennig / A. Bauer / Melissa A. Denecke / Th. Fanghänel
Published Online: 2009-09-25 | DOI: https://doi.org/10.1524/ract.92.3.133.30487

Summary

The structure parameters of the Am3+ aquo ion and of Am(III) sorbed onto smectite and kaolinite at varying pH are analyzed using EXAFS. An Am-O distance of 2.47-2.49Å is found and a coordination number of 8-9 oxygen atoms is observed for the Am3+ and its hydration sphere. Combined TRLFS (Cm(III)) and EXAFS (Am(III)) results show that An(III) sorbs onto smectite at pH 4, forming an outer-sphere complex and retains its complete primary hydration sphere. With increasing pH, inner-sphere sorption onto smectite and kaolinite occurs. The overall number of oxygen atoms coordinating the actinide ion remains about the same at pH 6, with four water molecules being replaced by oxygen atoms from the mineral surface during inner-sphere complex formation. The coordination number of sorbed Am(III) at pH 8 exhibits an apparent decrease, which may be affected by the formation of ternary OH-/Am/clay mineral surface species.

About the article

Published Online: 2009-09-25

Published in Print: 2004-03-01


Citation Information: Radiochimica Acta, ISSN (Online) 2193-3405, ISSN (Print) 0033-8230, DOI: https://doi.org/10.1524/ract.92.3.133.30487.

Export Citation

© 2004 Oldenbourg Wissenschaftsverlag GmbH. Copyright Clearance Center

Citing Articles

Here you can find all Crossref-listed publications in which this article is cited. If you would like to receive automatic email messages as soon as this article is cited in other publications, simply activate the “Citation Alert” on the top of this page.

[1]
Qun-Yan Wu, Yu-Ting Song, Lin Ji, Cong-Zhi Wang, Zhi-Fang Chai, and Wei-Qun Shi
Phys. Chem. Chem. Phys., 2017
[2]
Robert Polly, Frank Heberling, Bernd Schimmelpfennig, and Horst Geckeis
The Journal of Physical Chemistry C, 2017
[3]
Feng Ma, Qiang Jin, Ping Li, Zongyuan Chen, Jiachun Lu, Zhijun Guo, and Wangsuo Wu
Applied Geochemistry, 2017, Volume 84, Page 325
[5]
Maryline G. Ferrier, Benjamin W. Stein, Enrique R. Batista, John M. Berg, Eva R. Birnbaum, Jonathan W. Engle, Kevin D. John, Stosh A. Kozimor, Juan S. Lezama Pacheco, and Lindsay N. Redman
ACS Central Science, 2017, Volume 3, Number 3, Page 176
[6]
Shujun Yu, Xiangxue Wang, Shitong Yang, Guodong Sheng, Ahmed Alsaedi, Tasawar Hayat, and Xiangke Wang
Science China Chemistry, 2017, Volume 60, Number 2, Page 170
[7]
Parveen Kumar Verma and Prasanta Kumar Mohapatra
RSC Adv., 2016, Volume 6, Number 87, Page 84464
[8]
Maryline G. Ferrier, Enrique R. Batista, John M. Berg, Eva R. Birnbaum, Justin N. Cross, Jonathan W. Engle, Henry S. La Pierre, Stosh A. Kozimor, Juan S. Lezama Pacheco, Benjamin W. Stein, S. Chantal E. Stieber, and Justin J. Wilson
Nature Communications, 2016, Volume 7, Page 12312
[10]
Saptarshi Biswas, Robin Steudtner, Moritz Schmidt, Cora McKenna, Luis León Vintró, Brendan Twamley, and Robert J. Baker
Dalton Trans., 2016, Volume 45, Number 15, Page 6383
[11]
Matthieu Autillo, Laetitia Guerin, Hélène Bolvin, Philippe Moisy, and Claude Berthon
Phys. Chem. Chem. Phys., 2016, Volume 18, Number 9, Page 6515
[12]
Biswajit Sadhu, Mahesh Sundararajan, and Tusar Bandyopadhyay
Inorganic Chemistry, 2016, Volume 55, Number 2, Page 598
[13]
Takayuki Sasaki, Kenyou Ueda, Takumi Saito, Noboru Aoyagi, Taishi Kobayashi, Ikuji Takagi, Takaumi Kimura, and Yukio Tachi
Journal of Nuclear Science and Technology, 2016, Volume 53, Number 4, Page 592
[14]
N. Finck, K. Dardenne, and H. Geckeis
Chemical Geology, 2015, Volume 409, Page 12
[15]
Vicente Fiorini Stefani, Rommulo Vieira Conceição, Larissa Colombo Carniel, and Naira Maria Balzaretti
Applied Clay Science, 2014, Volume 102, Page 51
[16]
Yubing Sun, Jiaxing Li, and Xiangke Wang
Geochimica et Cosmochimica Acta, 2014, Volume 140, Page 621
[17]
Cong-Zhi Wang, Jian-Hui Lan, Qun-Yan Wu, Yu-Liang Zhao, Xiang-Ke Wang, Zhi-Fang Chai, and Wei-Qun Shi
Dalton Transactions, 2014, Volume 43, Number 23, Page 8713
[18]
Cong-Zhi Wang, Wei-Qun Shi, Jian-Hui Lan, Yu-Liang Zhao, Yue-Zhou Wei, and Zhi-Fang Chai
Inorganic Chemistry, 2013, Volume 52, Number 19, Page 10904
[19]
Shitong Yang, Guodong Sheng, Gilles Montavon, Zhiqiang Guo, Xiaoli Tan, Bernd Grambow, and Xiangke Wang
Geochimica et Cosmochimica Acta, 2013, Volume 121, Page 84
[20]
Juan Xi, Jian-Hui Lan, Gui-Wu Lu, Yu-Liang Zhao, Zhi-Fang Chai, and Wei-Qun Shi
Molecular Simulation, 2014, Volume 40, Number 5, Page 379
[21]
S. Kumar, A.S. Pente, R.K. Bajpai, C.P. Kaushik, and B.S. Tomar
Applied Geochemistry, 2013, Volume 35, Page 28
[22]
Xing Gao, GuoDong Sheng, and YuYing Huang
Science China Chemistry, 2013, Volume 56, Number 11, Page 1658
[23]
Md. Rabiul Awual, Tohru Kobayashi, Hideaki Shiwaku, Yuji Miyazaki, Ryuhei Motokawa, Sinichi Suzuki, Yoshihiro Okamoto, and Tsuyoshi Yaita
Chemical Engineering Journal, 2013, Volume 225, Page 558
[24]
Horst Geckeis, Johannes Lützenkirchen, Robert Polly, Thomas Rabung, and Moritz Schmidt
Chemical Reviews, 2013, Volume 113, Number 2, Page 1016
[25]
Kate Maher, John R. Bargar, and Gordon E. Brown
Inorganic Chemistry, 2013, Volume 52, Number 7, Page 3510
[26]
Karah E. Knope and L. Soderholm
Chemical Reviews, 2013, Volume 113, Number 2, Page 944
[27]
G. Lujanienė, P. Beneš, K. Štamberg, K. Jokšas, and I. Kulakauskaitė
Journal of Radioanalytical and Nuclear Chemistry, 2013, Volume 295, Number 3, Page 1957
[28]
N. Huittinen, Th. Rabung, A. Schnurr, M. Hakanen, J. Lehto, and H. Geckeis
Geochimica et Cosmochimica Acta, 2012, Volume 99, Page 100
[29]
P. R. Smirnov and V. N. Trostin
Russian Journal of General Chemistry, 2012, Volume 82, Number 7, Page 1204
[30]
M. Bouby, J. Lützenkirchen, K. Dardenne, T. Preocanin, M.A. Denecke, R. Klenze, and H. Geckeis
Journal of Colloid and Interface Science, 2010, Volume 350, Number 2, Page 551
[31]
N. Huittinen, Th. Rabung, J. Lützenkirchen, S.C. Mitchell, B.R. Bickmore, J. Lehto, and H. Geckeis
Journal of Colloid and Interface Science, 2009, Volume 332, Number 1, Page 158
[32]
T. Stumpf, M. Marques Fernandes, C. Walther, K. Dardenne, and Th. Fanghänel
Journal of Colloid and Interface Science, 2006, Volume 302, Number 1, Page 240
[33]
Eva Hartmann, Boris Brendebach, Robert Polly, Horst Geckeis, and Thorsten Stumpf
Journal of Colloid and Interface Science, 2011, Volume 353, Number 2, Page 562
[34]
Evgeny Galunin, María D. Alba, Maria J. Santos, Taufik Abrão, and Miquel Vidal
Geochimica et Cosmochimica Acta, 2010, Volume 74, Number 3, Page 862
[35]
E. Tertre, A. Hofmann, and G. Berger
Geochimica et Cosmochimica Acta, 2008, Volume 72, Number 4, Page 1043
[36]
P. Fenter, S.S. Lee, C. Park, L. Soderholm, R.E. Wilson, and O. Schwindt
Geochimica et Cosmochimica Acta, 2010, Volume 74, Number 24, Page 6984
[37]
Peter Mandaliev, Thorsten Stumpf, Jan Tits, Rainer Dähn, Clemens Walther, and Erich Wieland
Geochimica et Cosmochimica Acta, 2011, Volume 75, Number 8, Page 2017
[38]
E. Tertre, G. Berger, E. Simoni, S. Castet, E. Giffaut, M. Loubet, and H. Catalette
Geochimica et Cosmochimica Acta, 2006, Volume 70, Number 18, Page 4563
[39]
Heike Brandt, Dirk Bosbach, Petra J. Panak, and Thomas Fanghänel
Geochimica et Cosmochimica Acta, 2007, Volume 71, Number 1, Page 145
[40]
Volker Metz, Keren Amram, and Jiwchar Ganor
Geochimica et Cosmochimica Acta, 2005, Volume 69, Number 7, Page 1755
[41]
Th. Rabung, M.C. Pierret, A. Bauer, H. Geckeis, M.H. Bradbury, and B. Baeyens
Geochimica et Cosmochimica Acta, 2005, Volume 69, Number 23, Page 5393
[42]
J. Schott, M. Acker, A. Barkleit, V. Brendler, S. Taut, and G. Bernhard
Radiochimica Acta, 2012, Volume 100, Number 5, Page 315
[43]
Keisuke Ishida, Takumi Saito, Noboru Aoyagi, Takaumi Kimura, Ryuji Nagaishi, Shinya Nagasaki, and Satoru Tanaka
Journal of Colloid and Interface Science, 2012, Volume 374, Number 1, Page 258
[44]
Astrid Barkleit, Gerhard Geipel, Margret Acker, Steffen Taut, and Gert Bernhard
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2011, Volume 78, Number 1, Page 549
[45]
Jian-Hui Lan, Wei-Qun Shi, Li-Yong Yuan, Yi-Xiao Feng, Yu-Liang Zhao, and Zhi-Fang Chai
The Journal of Physical Chemistry A, 2012, Volume 116, Number 1, Page 504
[46]
GuoDong Sheng, ShiTong Yang, DongLin Zhao, Jiang Sheng, and XiangKe Wang
Science China Chemistry, 2012, Volume 55, Number 1, Page 182
[47]
Katja Schmeide and Gert Bernhard
Applied Geochemistry, 2010, Volume 25, Number 8, Page 1238
[48]
Sumit Kumar, Aishwarya S. Kar, D. Bhattacharyya, and B. S. Tomar
Journal of Radioanalytical and Nuclear Chemistry, 2012, Volume 294, Number 1, Page 109
[49]
Horst Geckeis and Thomas Rabung
Journal of Contaminant Hydrology, 2008, Volume 102, Number 3-4, Page 187
[51]
Katja Schmeide, Tobias Reich, Susanne Sachs, and Gert Bernhard
Inorganica Chimica Acta, 2006, Volume 359, Number 1, Page 237
[52]
Maria Konstantinou and Ioannis Pashalidis
International Journal of Environmental Technology and Management, 2010, Volume 12, Number 2/3/4, Page 322
[53]
Galina Lujanienė, Petr Beneš, Karel Štamberg, and Tomas Ščiglo
Journal of Environmental Radioactivity, 2012, Volume 108, Page 41
[54]
Guodong Sheng, Shitong Yang, Jiang Sheng, Jun Hu, Xiaoli Tan, and Xiangke Wang
Environmental Science & Technology, 2011, Volume 45, Number 18, Page 7718
[55]
A. Křepelová, Susanne Sachs, and Gert Bernhard
Radiochimica Acta, 2011, Volume 99, Number 5, Page 253
[57]
Maria Marques Fernandes, B. Baeyens, and Michael H. Bradbury
Radiochimica Acta, 2008, Volume 96, Number 9-11
[58]
Silvia Stumpf, Isabelle Billard, C. Gaillard, Petra J. Panak, and K. Dardenne
Radiochimica Acta, 2008, Volume 96, Number 1/2008, Page 1
[59]
E. Hartmann, H. Geckeis, Thomas Rabung, Johannes Lützenkirchen, and Thomas Fanghänel
Radiochimica Acta, 2008, Volume 96, Number 9-11
[60]
N. Huittinen, Thomas Rabung, P. Andrieux, Jukka Lehto, and H. Geckeis
Radiochimica Acta, 2010, Volume 98, Number 9-11, Page 613
[61]
Robert Polly, Bernd Schimmelpfennig, Thomas Rabung, Mathias Flörsheimer, Reinhardt Klenze, and H. Geckeis
Radiochimica Acta, 2010, Volume 98, Number 9-11, Page 627
[62]
Richard E. Wilson, Oliver Schwindt, Paul Fenter, and L. Soderholm
Radiochimica Acta, 2010, Volume 98, Number 7
[63]
Thomas Rabung, Horst Geckeis, X. K. Wang, Jörg Rothe, Melissa A. Denecke, R. Klenze, and Thomas Fanghänel
Radiochimica Acta, 2006, Volume 94, Number 9-11
[64]
Christos Apostolidis, Bernd Schimmelpfennig, Nicola Magnani, Patric Lindqvist-Reis, Olaf Walter, Richard Sykora, Alfred Morgenstern, Eric Colineau, Roberto Caciuffo, Reinhardt Klenze, Richard G. Haire, Jean Rebizant, Frank Bruchertseifer, and Thomas Fanghänel
Angewandte Chemie, 2010, Volume 122, Number 36, Page 6487
[65]
Christos Apostolidis, Bernd Schimmelpfennig, Nicola Magnani, Patric Lindqvist-Reis, Olaf Walter, Richard Sykora, Alfred Morgenstern, Eric Colineau, Roberto Caciuffo, Reinhardt Klenze, Richard G. Haire, Jean Rebizant, Frank Bruchertseifer, and Thomas Fanghänel
Angewandte Chemie International Edition, 2010, Volume 49, Number 36, Page 6343
[67]
J. Wiebke, A. Moritz, X. Cao, and M. Dolg
Phys. Chem. Chem. Phys., 2007, Volume 9, Number 4, Page 459
[68]
Patric Lindqvist-Reis, Christos Apostolidis, Jean Rebizant, Alfred Morgenstern, Reinhardt Klenze, Olaf Walter, Thomas Fanghänel, and Richard G. Haire
Angewandte Chemie International Edition, 2007, Volume 46, Number 6, Page 919
[69]
Patric Lindqvist-Reis, Christos Apostolidis, Jean Rebizant, Alfred Morgenstern, Reinhardt Klenze, Olaf Walter, Thomas Fanghänel, and Richard G. Haire
Angewandte Chemie, 2007, Volume 119, Number 6, Page 937

Comments (0)

Please log in or register to comment.
Log in