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Radiochimica Acta

International Journal for chemical aspects of nuclear science and technology

Editor-in-Chief: Qaim, Syed M.

12 Issues per year


IMPACT FACTOR 2017: 1.202

CiteScore 2017: 1.22

SCImago Journal Rank (SJR) 2017: 0.409
Source Normalized Impact per Paper (SNIP) 2017: 0.869

Online
ISSN
2193-3405
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Volume 92, Issue 7

Issues

Anion-exchange behavior of Mo and W as homologs of Sg (element 106) in HCl and HNO3 as well as in mixed HCl-HF and HNO3-HF solutions

A. Kronenberg / P. K. Mohapatra / Jens Volker Kratz / G. Pfrepper / R. Pfrepper
Published Online: 2009-09-25 | DOI: https://doi.org/10.1524/ract.92.7.395.35747

Summary

We have determined Kd values for Mo and W in batch experiments on various anion-exchange resins in HCl and HNO3 as well as in mixed HCl-HF and HNO3-HF solutions in order to create a data base and to select optimum conditions for the determination of Kd values of Sg (element 106) in a future on-line experiment using continuous chromatography with the multi-column technique (MCT). Their influence by hydrolysis and fluoride complexation is discussed and the average charge of the complexes is determined from slope analyses. It is shown that the selectivity of anion exchangers for the Mo- and W complexes and, thus, the separation factors between them, depend strongly on the choice of the functional group of the anion-exchange resin.

About the article

Published Online: 2009-09-25

Published in Print: 2004-07-01


Citation Information: Radiochimica Acta, Volume 92, Issue 7, Pages 395–403, ISSN (Online) 2193-3405, ISSN (Print) 0033-8230, DOI: https://doi.org/10.1524/ract.92.7.395.35747.

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