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Radiochimica Acta

International Journal for chemical aspects of nuclear science and technology

Editor-in-Chief: Qaim, Syed M.


IMPACT FACTOR 2017: 1.202

CiteScore 2017: 1.22

SCImago Journal Rank (SJR) 2017: 0.409
Source Normalized Impact per Paper (SNIP) 2017: 0.869

Online
ISSN
2193-3405
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Volume 93, Issue 9-10

Issues

The effect of parameter uncertainty on blind prediction of Np(V) sorption onto hematite using the Diffuse Double Layer Model

Anke Richter / V. Brendler / C. Nebelung
Published Online: 2009-09-25 | DOI: https://doi.org/10.1524/ract.2005.93.9-10.527

Summary

The aim of this work is to illustrate the effect of parameter uncertainty (protolysis constants) in surface complexation modeling. As example the blind prediction of Np(V) sorption onto hematite was selected, applying the Diffuse Double Layer Model (DDLM).

None of the pK parameter sets randomly generated within a space of two standard deviations did deliver unacceptable predictions for the distribution coefficients. Thus, the formally large spreading of the pK values as extracted from literature (even after normalization and extrapolation to infinite dilution) is actually not critical. For well-defined mineral systems, provided a suitable database is accessible, the DDLM approach seems to be promising.

Keywords: Sorption; Database; Diffuse Double Layer Model; Uncertainty analysis; Neptunyl; Hematite

About the article

Received: 2005-01-10

Accepted: 2005-06-10

Published Online: 2009-09-25

Published in Print: 2005-09-01


Citation Information: Radiochimica Acta, Volume 93, Issue 9-10, Pages 527–531, ISSN (Online) 2193-3405, ISSN (Print) 0033-8230, DOI: https://doi.org/10.1524/ract.2005.93.9-10.527.

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