International Journal for chemical aspects of nuclear science and technology
Editor-in-Chief: Qaim, Syed M.
12 Issues per year
IMPACT FACTOR 2017: 1.202
CiteScore 2017: 1.22
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Source Normalized Impact per Paper (SNIP) 2017: 0.869
Hexafluoro complex of rutherfordium in mixed HF/HNO3 solutions
Formation of anionic fluoride-complexes of element 104, rutherfordium, produced in the 248Cm(18O,5n) 261Rf reaction was studied by anion-exchange on an atom-at-a-time scale. It was found that the hexafluoro complex of Rf, [RfF6]2−, was formed in the studied fluoride ion concentrations of 0.0005–0.013 M. Formation of [RfF6]2− was significantly different from that of the homologues Zr and Hf, [ZrF6]2− and [HfF6]2−; the evaluated formation constant of [RfF6]2− is at least one-order of magnitude smaller than those of [ZrF6]2− and [HfF6]2−.
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