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Radiochimica Acta

International Journal for chemical aspects of nuclear science and technology

Editor-in-Chief: Qaim, Syed M.

12 Issues per year


IMPACT FACTOR 2017: 1.202

CiteScore 2017: 1.22

SCImago Journal Rank (SJR) 2017: 0.409
Source Normalized Impact per Paper (SNIP) 2017: 0.869

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2193-3405
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Volume 96, Issue 3

Issues

Hexafluoro complex of rutherfordium in mixed HF/HNO3 solutions

A. Toyoshima / H. Haba / K. Tsukada / M. Asai / K. Akiyama / S. Goto / Y. Ishii / I. Nishinaka / T. K. Sato / Yuichi Nagame / Wataru Sato / Yuuki Tani / H. Hasegawa / K. Matsuo / D. Saika / Y. Kitamoto / A. Shinohara / M. Ito / J. Saito / H. Kudo / A. Yokoyama / M. Sakama / K. Sueki / Y. Oura / H. Nakahara / M. Schädel / W. Brüchle / J. V. Kratz
Published Online: 2009-09-25 | DOI: https://doi.org/10.1524/ract.2008.1474

Summary

Formation of anionic fluoride-complexes of element 104, rutherfordium, produced in the 248Cm(18O,5n) 261Rf reaction was studied by anion-exchange on an atom-at-a-time scale. It was found that the hexafluoro complex of Rf, [RfF6]2−, was formed in the studied fluoride ion concentrations of 0.0005–0.013 M. Formation of [RfF6]2− was significantly different from that of the homologues Zr and Hf, [ZrF6]2− and [HfF6]2−; the evaluated formation constant of [RfF6]2− is at least one-order of magnitude smaller than those of [ZrF6]2− and [HfF6]2−.

Keywords: Rutherfordium (Rf); Zirconium (Zr); Hafnium (Hf); Atom-at-a-time chemistry; Hexafluoro complex; Anion-exchange chromatography

About the article

Received: 2007-06-15

Accepted: 2007-10-12

Published Online: 2009-09-25

Published in Print: 2008-03-01


Citation Information: Radiochimica Acta, Volume 96, Issue 3, Pages 125–134, ISSN (Print) 0033-8230, DOI: https://doi.org/10.1524/ract.2008.1474.

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A. Toyoshima, K. Ooe, S. Miyashita, M. Asai, M. F. Attallah, N. Goto, N. S. Gupta, H. Haba, M. Huang, J. Kanaya, Y. Kaneya, Y. Kasamatsu, Y. Kitatsuji, Y. Kitayama, K. Koga, Y. Komori, T. Koyama, J. V. Kratz, H. V. Lerum, Y. Oshimi, V. Pershina, D. Sato, T. K. Sato, Y. Shigekawa, A. Shinohara, A. Tanaka, K. Tsukada, S. Tsuto, T. Yokokita, A. Yokoyama, J. P. Omtvedt, Y. Nagame, and M. Schädel
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K. Ooe, M. F. Attallah, M. Asai, N. Goto, N. S. Gupta, H. Haba, M. Huang, J. Kanaya, Y. Kaneya, Y. Kasamatsu, Y. Kitatsuji, Y. Kitayama, K. Koga, Y. Komori, T. Koyama, J. V. Kratz, H. V. Lerum, S. Miyashita, Y. Oshimi, V. Pershina, D. Sato, T. K. Sato, Y. Shigekawa, A. Shinohara, A. Tanaka, A. Toyoshima, K. Tsukada, S. Tsuto, T. Yokokita, A. Yokoyama, J. P. Omtvedt, Y. Nagame, and M. Schädel
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X. H. Liang, K. Tsukada, A. Toyoshima, Z. J. Li, M. Asai, T. K. Sato, N. Sato, and Y. Nagame
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Z. J. Li, A. Toyoshima, M. Asai, K. Tsukada, T. K. Sato, N. Sato, T. Kikuchi, Y. Nagame, M. Schädel, Valeria Pershina, and X. H. Liang
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Kazuaki Tsukada, H. Haba, M. Asai, A. Toyoshima, K. Akiyama, Y. Kasamatsu, I. Nishinaka, S. Ichikawa, K. Yasuda, Y. Miyamoto, Kazuyuki Hashimoto, and et al.
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S. A. Cotton
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