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Radiochimica Acta

International Journal for chemical aspects of nuclear science and technology

Editor-in-Chief: Qaim, Syed M.

12 Issues per year


IMPACT FACTOR 2017: 1.202

CiteScore 2017: 1.22

SCImago Journal Rank (SJR) 2017: 0.409
Source Normalized Impact per Paper (SNIP) 2017: 0.869

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2193-3405
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Volume 97, Issue 2

Issues

Adsorption of Db and its homologues Nb and Ta, and the pseudo-homologue Pa on anion-exchange resin in HF solution

Kazuaki Tsukada / H. Haba / M. Asai / A. Toyoshima
  • 2 Japan Atomic Energy Research Institute, Advanced Science Research Center, Tokai, Ibaraki 319-1195, Japan
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ K. Akiyama / Y. Kasamatsu / I. Nishinaka / S. Ichikawa / K. Yasuda / Y. Miyamoto / Kazuyuki Hashimoto
  • 7 Japan Atomic Energy Research Institute, Department of Research Reactor, Ibaraki-ken, Japan
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ et al.
Published Online: 2009-09-25 | DOI: https://doi.org/10.1524/ract.2009.1577

Abstract

Anion-exchange chromatography of element 105, dubnium (Db), produced in the 248Cm( 19F, 5n) 262Db reaction is investigated together with the homologues Nb and Ta, and the pseudo-homologue Pa in 13.9 M hydrofluoric acid (HF) solution. The distribution coefficient (Kd) of Db on an anion-exchange resin is successfully determined by running cycles of 1702 chromatographic column separations. The result clearly indicates that the adsorption of Db on the resin is significantly different from that of the homologues and that the adsorption of anionic fluoro complexes of these elements decreases in the sequence of Ta≈ Nb>Db≥Pa.

Keywords: Dubnium (Db); Anion-exchange chromatography; Hydrofluoric acid; Fluoride complexation; Atom-at-a-time chemistry

About the article

* Correspondence address: Advanced Science Research Center, Japan Atomic Energy Agency, Tokai-Mura, 319-1195 Ibaraki, Japan,


Published Online: 2009-09-25

Published in Print: 2009-02-01


Citation Information: Radiochimica Acta International journal for chemical aspects of nuclear science and technology, Volume 97, Issue 2, Pages 83–89, ISSN (Print) 0033-8230, DOI: https://doi.org/10.1524/ract.2009.1577.

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