International Journal for chemical aspects of nuclear science and technology
Editor-in-Chief: Qaim, Syed M.
12 Issues per year
IMPACT FACTOR 2017: 1.202
CiteScore 2017: 1.22
SCImago Journal Rank (SJR) 2017: 0.409
Source Normalized Impact per Paper (SNIP) 2017: 0.869
Adsorption of Db and its homologues Nb and Ta, and the pseudo-homologue Pa on anion-exchange resin in HF solution
Anion-exchange chromatography of element 105, dubnium (Db), produced in the 248Cm( 19F, 5n) 262Db reaction is investigated together with the homologues Nb and Ta, and the pseudo-homologue Pa in 13.9 M hydrofluoric acid (HF) solution. The distribution coefficient (Kd) of Db on an anion-exchange resin is successfully determined by running cycles of 1702 chromatographic column separations. The result clearly indicates that the adsorption of Db on the resin is significantly different from that of the homologues and that the adsorption of anionic fluoro complexes of these elements decreases in the sequence of Ta≈ Nb>Db≥Pa.
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